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- W3195408966 abstract "Zinc oxide is a key material in catalysis. Designing of ZnO crystal aggregates with the surface defect has received significant attention. Herein, we synthesized ZnO aggregates with tiny primary nanoparticles through a mechanochemistry-assisted salt-templating (potassium chloride) method. Interestingly, this KCl-templating strategy could lead to significant increase in specific surface area (SSA) of ZnO (up to 91 m2/g), whereas commercial ZnO-COM has a SSA of 5 m2/g. Meanwhile, this strategy via ZnCl2-KCl solid solution has also created a number of oxygen vacancies into ZnO aggregates. With these attractive features, as-made Pd-ZnO catalyst showed outstanding performance in methanol steam reforming, especially at low temperature (20 % Conversion and 95 % CO2 Selectivity at 150 °C). Current strategy provides a gateway for the rational design of ZnO-based catalytic materials." @default.
- W3195408966 created "2021-08-30" @default.
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- W3195408966 date "2021-12-01" @default.
- W3195408966 modified "2023-10-09" @default.
- W3195408966 title "Mechanochemical Alkali-Metal-Salt-mediated synthesis of ZnO nanocrystals with abundant oxygen Vacancies: An efficient support for Pd-based catalyst" @default.
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- W3195408966 doi "https://doi.org/10.1016/j.cej.2021.131757" @default.
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