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- W3195427858 abstract "Palladium and acid cooperative catalysis is presented as a strategy for the [3 + 2] cycloaddition of acceptor/donor-type diazo compounds with terminal alkynes. The [3 + 2] cycloaddition of α-aryl-α-diazoacetates with terminal alkynes proceeded smoothly to produce 2,3,5-trisubstituted furans with high yields. This synthesis method provided a direct and efficient pathway to prepare furan ring-containing organosilane and organoboron reagents. Synthetically valuable functional groups such as chloro and bromo atoms, methoxycarbonyl, and carbonyl remained intact during the [3 + 2] cycloaddition reaction." @default.
- W3195427858 created "2021-08-30" @default.
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- W3195427858 date "2021-08-16" @default.
- W3195427858 modified "2023-10-06" @default.
- W3195427858 title "[3 + 2] Cycloaddition of α-Aryl-α-diazoacetates with Terminal Alkynes via the Cooperative Catalysis of Palladium and Acid" @default.
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- W3195427858 doi "https://doi.org/10.1021/acscatal.1c02533" @default.
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