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• W3195601514 abstract "Copper (II) ions have been shown to greatly improve the chemical stability and peroxidase-like activity of gold nanoclusters (AuNCs). Since the affinity between Cu2+ and pyrophosphate (PPi) is higher than that between Cu2+ and AuNCs, the catalytic activity of AuNCs-Cu2+ decreases with the introduction of PPi. Based on this principle, a new colorimetric detection method of PPi with high sensitivity and selectivity was developed by using AuNCs-Cu2+ as a probe. Under optimized conditions, the detection limit of PPi was 0.49 nM with a linear range of 0.51 to 30,000 nM. The sensitivity of the method was three orders of magnitude higher than that of a fluorescence method using AuNCs-Cu2+ as the probe. Finally, the AuNCs-Cu2+ system was successfully applied to directly determine the concentration of PPi in human urine samples." @default.
• W3195601514 created "2021-08-30" @default.
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• W3195601514 date "2021-08-17" @default.
• W3195601514 modified "2023-10-12" @default.
• W3195601514 title "Copper (II) Ion-Modified Gold Nanoclusters as Peroxidase Mimetics for the Colorimetric Detection of Pyrophosphate" @default.
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• W3195601514 doi "https://doi.org/10.3390/s21165538" @default.
• W3195601514 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8400922" @default.
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