FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3195909769> ?p ?o ?g. }

• W3195909769 endingPage "3389" @default.
• W3195909769 startingPage "3377" @default.
• W3195909769 abstract "ConspectusThis Account highlights recent experimental and theoretical work focusing on the development of polyoxometalates (POMs) as possible active switching units in what may be called “molecule-based memory cells”. Herein, we critically discuss how multiply charged vanadium-containing POMs, which exhibit stable metal–oxo bonds and are characterized by the excellent ability to change their redox states without significant structural distortions of the central polyoxoanion core, can be immobilized best and how they may work optimally at appropriate surfaces. Furthermore, we critically discuss important issues and challenges on the long way toward POM-based nanoelectronics. This Account is divided into four sections shedding light on POM interplay in solution and on surfaces, ion soft-landing of mass-selected POMs on surfaces, electronic modification of POMs on surfaces, and computational modeling of POMs on surfaces. The sections showcase the complex nature of far-reaching POM interactions with the chemical surroundings in solution and the properties of POMs in the macroscopic environment of electrode surfaces. Section 2 describes complex relationships of POMs with their counter-cations, solvent molecules, and water impurities, which have been shown to exhibit a direct impact on the resulting surface morphology, where a concentration-dependent formation of micellar structures can be potentially observed. Section 3 gives insights into the ion soft-landing deposition of mass-selected POMs on electrode surfaces, which emerges as an appealing method because the simultaneous deposition of agglomeration-stimulating counter-cations can be avoided. Section 4 provides details of electronic properties of POMs and their modification by external electronic stimuli toward the development of multiple-state resistive (memristive) switches. Section 5 sheds light on issues of the determination of the electronic structure properties of POMs across their interfaces, which is difficult to address by experiment. The studies summarized in these four sections have employed various X-ray-scattering, microscopy, spectroscopy, and computational techniques for imaging of POM interfaces in solution and on surfaces to determine the adsorption type, agglomeration tendency, distribution, and oxidation state of deposited molecules. The presented research findings and conceptual ideas may assist experimentalists and theoreticians to advance the exploration of POM electrical conductivity as a function of metal redox and spin states and to pave the way for a realization of (“brain-inspired”) POM-based memory devices, memristive POM-surface device engineering, and energy efficient nonvolatile data storage and processing technologies." @default.
• W3195909769 created "2021-08-30" @default.
• W3195909769 creator A5000256850 @default.
• W3195909769 creator A5005620103 @default.
• W3195909769 creator A5013260584 @default.
• W3195909769 creator A5028995502 @default.
• W3195909769 creator A5051798789 @default.
• W3195909769 creator A5073943181 @default.
• W3195909769 date "2021-08-24" @default.
• W3195909769 modified "2023-10-16" @default.
• W3195909769 title "Insights from Adsorption and Electron Modification Studies of Polyoxometalates on Surfaces for Molecular Memory Applications" @default.
• W3195909769 cites W1806369898 @default.
• W3195909769 cites W1984836820 @default.
• W3195909769 cites W1985252301 @default.
• W3195909769 cites W1995286511 @default.
• W3195909769 cites W2007065748 @default.
• W3195909769 cites W2014375670 @default.
• W3195909769 cites W2016922062 @default.
• W3195909769 cites W2018774711 @default.
• W3195909769 cites W2021656562 @default.
• W3195909769 cites W2041655819 @default.
• W3195909769 cites W2045197688 @default.
• W3195909769 cites W2049111601 @default.
• W3195909769 cites W2071947829 @default.
• W3195909769 cites W2074357625 @default.
• W3195909769 cites W2082222323 @default.
• W3195909769 cites W2101544397 @default.
• W3195909769 cites W2128629345 @default.
• W3195909769 cites W2131289074 @default.
• W3195909769 cites W2136300394 @default.
• W3195909769 cites W2136424830 @default.
• W3195909769 cites W2137249916 @default.
• W3195909769 cites W2163501288 @default.
• W3195909769 cites W2233429724 @default.
• W3195909769 cites W2277880030 @default.
• W3195909769 cites W2288222136 @default.
• W3195909769 cites W2315661982 @default.
• W3195909769 cites W2329245385 @default.
• W3195909769 cites W2337719919 @default.
• W3195909769 cites W2339059891 @default.
• W3195909769 cites W2549384179 @default.
• W3195909769 cites W2554929239 @default.
• W3195909769 cites W2586378907 @default.
• W3195909769 cites W2604330189 @default.
• W3195909769 cites W2609722714 @default.
• W3195909769 cites W2758012365 @default.
• W3195909769 cites W2761270525 @default.
• W3195909769 cites W2765531621 @default.
• W3195909769 cites W2787956937 @default.
• W3195909769 cites W2789540444 @default.
• W3195909769 cites W2800734161 @default.
• W3195909769 cites W2804580131 @default.
• W3195909769 cites W2809444559 @default.
• W3195909769 cites W2886024813 @default.
• W3195909769 cites W2888091641 @default.
• W3195909769 cites W2889506486 @default.
• W3195909769 cites W2901572725 @default.
• W3195909769 cites W2902296014 @default.
• W3195909769 cites W2903071893 @default.
• W3195909769 cites W2903113490 @default.
• W3195909769 cites W2909921154 @default.
• W3195909769 cites W2923082667 @default.
• W3195909769 cites W2945642016 @default.
• W3195909769 cites W2953983428 @default.
• W3195909769 cites W2971126584 @default.
• W3195909769 cites W2980259143 @default.
• W3195909769 cites W2982222559 @default.
• W3195909769 cites W2993595667 @default.
• W3195909769 cites W3009887490 @default.
• W3195909769 cites W3012123722 @default.
• W3195909769 cites W3023587085 @default.
• W3195909769 cites W3091364089 @default.
• W3195909769 cites W3093483053 @default.
• W3195909769 cites W3098045899 @default.
• W3195909769 cites W3101494080 @default.
• W3195909769 cites W3122103647 @default.
• W3195909769 cites W3123368982 @default.
• W3195909769 cites W3128914866 @default.
• W3195909769 cites W3129246086 @default.
• W3195909769 cites W3140245974 @default.
• W3195909769 cites W3165538011 @default.
• W3195909769 cites W3174458474 @default.
• W3195909769 cites W656433898 @default.
• W3195909769 cites W656973856 @default.
• W3195909769 doi "https://doi.org/10.1021/acs.accounts.1c00311" @default.
• W3195909769 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34427081" @default.
• W3195909769 hasPublicationYear "2021" @default.
• W3195909769 type Work @default.
• W3195909769 sameAs 3195909769 @default.
• W3195909769 citedByCount "14" @default.
• W3195909769 countsByYear W31959097692021 @default.
• W3195909769 countsByYear W31959097692022 @default.
• W3195909769 countsByYear W31959097692023 @default.
• W3195909769 crossrefType "journal-article" @default.
• W3195909769 hasAuthorship W3195909769A5000256850 @default.
• W3195909769 hasAuthorship W3195909769A5005620103 @default.
• W3195909769 hasAuthorship W3195909769A5013260584 @default.
• W3195909769 hasAuthorship W3195909769A5028995502 @default.

• next