Matches in SemOpenAlex for { <https://semopenalex.org/work/W3195969281> ?p ?o ?g. }
- W3195969281 endingPage "35652" @default.
- W3195969281 startingPage "35641" @default.
- W3195969281 abstract "This study aims to present the hydro-catalytic treatment of organoamine boranes for efficient thermal dehydrogenation for hydrogen production. Organoamine boranes, methylamine borane (MeAB), and ethane 1,2 diamine borane (EDAB), known as ammonia borane (AB) carbon derivatives, are synthesized to be used as a solid-state hydrogen storage medium. Thermal dehydrogenation of MeAB and EDAB is performed at 80 °C, 100 °C, and 120 °C under different conditions (self, catalytic, and hydro-catalytic) for hydrogen production and compared with AB. For this purpose, a cobalt-doped activated carbon (Co-AC) catalyst is fabricated. The physicochemical properties of Co-AC catalyst is investigated by well-known techniques such as ATR/FT-IR, XRD, XPS, ICP-MS, BET, and TEM. The synthesized Co-AC catalyst obtained in nano CoOOH structure (20 nm, 12% Co wt) is formed and well-dispersed on the activated carbon support. It has indicated that Co-AC exhibits efficient catalytic activity towards organoamine boranes thermal dehydrogenation. Hydrogen release tests show that hydro-catalytic treatment improves the thermal dehydrogenation kinetics of neat MeAB, EDAB, and AB. Co-AC catalyzed hydro-treatment for thermal dehydrogenation of MeAB and EDAB acceleras the hydrogen release from 0.13 mL H2/min to 46.12 mL H2/min, from 0.16 mL H2/min to 38.06 mL H2/min, respectively at 80 °C. Moreover, hydro-catalytic treatment significantly lowers the H2 release barrier of organoamine boranes thermal dehydrogenation, from 110 kJ/mol to 19 kJ/mol for MeAB and 130 kJ/mol to 21 kJ/mol for EDAB. In conclusion, hydro and catalytic treatment presents remarkable synergistic effect in thermal dehydrogenation and improves the hydrogen release kinetics." @default.
- W3195969281 created "2021-08-30" @default.
- W3195969281 creator A5058653488 @default.
- W3195969281 creator A5076375568 @default.
- W3195969281 date "2021-10-01" @default.
- W3195969281 modified "2023-10-14" @default.
- W3195969281 title "Hydro-catalytic treatment of organoamine boranes for efficient thermal dehydrogenation for hydrogen production" @default.
- W3195969281 cites W1651934301 @default.
- W3195969281 cites W1931739045 @default.
- W3195969281 cites W1965295058 @default.
- W3195969281 cites W1973197444 @default.
- W3195969281 cites W1981236824 @default.
- W3195969281 cites W1999218445 @default.
- W3195969281 cites W2002825129 @default.
- W3195969281 cites W2003135537 @default.
- W3195969281 cites W2044076915 @default.
- W3195969281 cites W2047437635 @default.
- W3195969281 cites W2081768728 @default.
- W3195969281 cites W2083876961 @default.
- W3195969281 cites W2090780090 @default.
- W3195969281 cites W2100553252 @default.
- W3195969281 cites W2138520791 @default.
- W3195969281 cites W2151588309 @default.
- W3195969281 cites W2253165797 @default.
- W3195969281 cites W2326680219 @default.
- W3195969281 cites W2520909911 @default.
- W3195969281 cites W2533273274 @default.
- W3195969281 cites W2554639915 @default.
- W3195969281 cites W2597794493 @default.
- W3195969281 cites W2600167861 @default.
- W3195969281 cites W2626626389 @default.
- W3195969281 cites W2768453478 @default.
- W3195969281 cites W2777488888 @default.
- W3195969281 cites W2795498572 @default.
- W3195969281 cites W2805648916 @default.
- W3195969281 cites W2810906740 @default.
- W3195969281 cites W2886243696 @default.
- W3195969281 cites W2904995800 @default.
- W3195969281 cites W2915614672 @default.
- W3195969281 cites W2922050496 @default.
- W3195969281 cites W2924309533 @default.
- W3195969281 cites W2973086832 @default.
- W3195969281 cites W2974255318 @default.
- W3195969281 cites W3006461856 @default.
- W3195969281 cites W3008812596 @default.
- W3195969281 cites W3011402549 @default.
- W3195969281 cites W3024760661 @default.
- W3195969281 cites W3045708520 @default.
- W3195969281 cites W3047491231 @default.
- W3195969281 cites W3089797259 @default.
- W3195969281 cites W3112543436 @default.
- W3195969281 cites W3123548164 @default.
- W3195969281 doi "https://doi.org/10.1016/j.ijhydene.2021.08.133" @default.
- W3195969281 hasPublicationYear "2021" @default.
- W3195969281 type Work @default.
- W3195969281 sameAs 3195969281 @default.
- W3195969281 citedByCount "9" @default.
- W3195969281 countsByYear W31959692812021 @default.
- W3195969281 countsByYear W31959692812022 @default.
- W3195969281 countsByYear W31959692812023 @default.
- W3195969281 crossrefType "journal-article" @default.
- W3195969281 hasAuthorship W3195969281A5058653488 @default.
- W3195969281 hasAuthorship W3195969281A5076375568 @default.
- W3195969281 hasConcept C119889771 @default.
- W3195969281 hasConcept C150394285 @default.
- W3195969281 hasConcept C161790260 @default.
- W3195969281 hasConcept C178790620 @default.
- W3195969281 hasConcept C179104552 @default.
- W3195969281 hasConcept C185592680 @default.
- W3195969281 hasConcept C202189072 @default.
- W3195969281 hasConcept C2778470625 @default.
- W3195969281 hasConcept C2778553741 @default.
- W3195969281 hasConcept C2779647737 @default.
- W3195969281 hasConcept C501308230 @default.
- W3195969281 hasConcept C512968161 @default.
- W3195969281 hasConcept C68044625 @default.
- W3195969281 hasConceptScore W3195969281C119889771 @default.
- W3195969281 hasConceptScore W3195969281C150394285 @default.
- W3195969281 hasConceptScore W3195969281C161790260 @default.
- W3195969281 hasConceptScore W3195969281C178790620 @default.
- W3195969281 hasConceptScore W3195969281C179104552 @default.
- W3195969281 hasConceptScore W3195969281C185592680 @default.
- W3195969281 hasConceptScore W3195969281C202189072 @default.
- W3195969281 hasConceptScore W3195969281C2778470625 @default.
- W3195969281 hasConceptScore W3195969281C2778553741 @default.
- W3195969281 hasConceptScore W3195969281C2779647737 @default.
- W3195969281 hasConceptScore W3195969281C501308230 @default.
- W3195969281 hasConceptScore W3195969281C512968161 @default.
- W3195969281 hasConceptScore W3195969281C68044625 @default.
- W3195969281 hasFunder F4320323955 @default.
- W3195969281 hasIssue "72" @default.
- W3195969281 hasLocation W31959692811 @default.
- W3195969281 hasOpenAccess W3195969281 @default.
- W3195969281 hasPrimaryLocation W31959692811 @default.
- W3195969281 hasRelatedWork W1582021872 @default.
- W3195969281 hasRelatedWork W2013424504 @default.
- W3195969281 hasRelatedWork W2374615261 @default.
- W3195969281 hasRelatedWork W2417330610 @default.