Matches in SemOpenAlex for { <https://semopenalex.org/work/W3195991010> ?p ?o ?g. }
- W3195991010 endingPage "8087" @default.
- W3195991010 startingPage "8077" @default.
- W3195991010 abstract "Acting as soft-nanoparticles, series of microgels are microemulsion polymerized and investigated for their dynamics in the melt state. Each series is kept at the same average number of repeating units between crosslinking points, in short, the crosslinking degree. The relaxation time increases at the 30th power of their diameters or 10th power of their molecular weights or volume and then diverges upon approaching the critical diameter. Our proposed equation describes their relaxation time as a function of diameter and crosslinking degree and unifies both our and literature data. Soft-nanoparticles larger than the critical diameter cannot relax in the melt state within the experimental limits. This may serve as the boundary between thermal molecular or macromolecular domains and the athermal colloidal domain. This critical diameter obeys 1/3 power of the crosslinking degree. This agrees with the Hertzian contact model and the stress originates from elastic deformation. This scaling also implies that the boundary is where SNPs contain a constant number of crosslinking points, around 200. Our equation foresees that for the same molecular weight while changing the topology from linear chains to more and more elastic soft-nanoparticles the relaxation time should first decrease and then increase to infinity. The initial decrease is more dramatic for lower molecular weights." @default.
- W3195991010 created "2021-08-30" @default.
- W3195991010 creator A5014053571 @default.
- W3195991010 creator A5047192904 @default.
- W3195991010 creator A5052921976 @default.
- W3195991010 creator A5053457827 @default.
- W3195991010 creator A5059498520 @default.
- W3195991010 creator A5062802300 @default.
- W3195991010 creator A5084670146 @default.
- W3195991010 date "2021-08-18" @default.
- W3195991010 modified "2023-09-30" @default.
- W3195991010 title "Diameter and Elasticity Governing the Relaxation of Soft-Nanoparticle Melts" @default.
- W3195991010 cites W1202966550 @default.
- W3195991010 cites W1967303178 @default.
- W3195991010 cites W1972675654 @default.
- W3195991010 cites W1975917272 @default.
- W3195991010 cites W1980074085 @default.
- W3195991010 cites W1983653705 @default.
- W3195991010 cites W1984080259 @default.
- W3195991010 cites W1985056742 @default.
- W3195991010 cites W1990052292 @default.
- W3195991010 cites W1993826366 @default.
- W3195991010 cites W1998876956 @default.
- W3195991010 cites W1999901649 @default.
- W3195991010 cites W2000199720 @default.
- W3195991010 cites W2002622418 @default.
- W3195991010 cites W2007215624 @default.
- W3195991010 cites W2010087734 @default.
- W3195991010 cites W2015996045 @default.
- W3195991010 cites W2029642921 @default.
- W3195991010 cites W2033954828 @default.
- W3195991010 cites W2035470914 @default.
- W3195991010 cites W2037710572 @default.
- W3195991010 cites W2040143461 @default.
- W3195991010 cites W2042399894 @default.
- W3195991010 cites W2051893661 @default.
- W3195991010 cites W2052673866 @default.
- W3195991010 cites W2052971487 @default.
- W3195991010 cites W2061528178 @default.
- W3195991010 cites W2061952589 @default.
- W3195991010 cites W2063750232 @default.
- W3195991010 cites W2066394480 @default.
- W3195991010 cites W2068145833 @default.
- W3195991010 cites W2068716729 @default.
- W3195991010 cites W2068873743 @default.
- W3195991010 cites W2073552286 @default.
- W3195991010 cites W2079539854 @default.
- W3195991010 cites W2080390601 @default.
- W3195991010 cites W2082151051 @default.
- W3195991010 cites W2082743808 @default.
- W3195991010 cites W2085618467 @default.
- W3195991010 cites W2086846094 @default.
- W3195991010 cites W2094368214 @default.
- W3195991010 cites W2103294193 @default.
- W3195991010 cites W2120424279 @default.
- W3195991010 cites W2131923581 @default.
- W3195991010 cites W2139603615 @default.
- W3195991010 cites W2145786037 @default.
- W3195991010 cites W2150502042 @default.
- W3195991010 cites W2157498061 @default.
- W3195991010 cites W2161814474 @default.
- W3195991010 cites W2430224017 @default.
- W3195991010 cites W2512519373 @default.
- W3195991010 cites W2522216497 @default.
- W3195991010 cites W2587840466 @default.
- W3195991010 cites W2609997138 @default.
- W3195991010 cites W2731804270 @default.
- W3195991010 cites W2743327261 @default.
- W3195991010 cites W2752845074 @default.
- W3195991010 cites W2764160394 @default.
- W3195991010 cites W2765711582 @default.
- W3195991010 cites W2785843069 @default.
- W3195991010 cites W2800641253 @default.
- W3195991010 cites W2898669006 @default.
- W3195991010 cites W2901884840 @default.
- W3195991010 cites W2904643719 @default.
- W3195991010 cites W2946033120 @default.
- W3195991010 cites W2947202475 @default.
- W3195991010 cites W2951585396 @default.
- W3195991010 cites W2952229992 @default.
- W3195991010 cites W2971913725 @default.
- W3195991010 cites W2991879068 @default.
- W3195991010 cites W3000470956 @default.
- W3195991010 cites W3009986965 @default.
- W3195991010 cites W3027224134 @default.
- W3195991010 cites W3085224254 @default.
- W3195991010 cites W3085406162 @default.
- W3195991010 cites W3090207775 @default.
- W3195991010 cites W3101300944 @default.
- W3195991010 cites W3101712865 @default.
- W3195991010 cites W3129862458 @default.
- W3195991010 cites W3178780388 @default.
- W3195991010 cites W86053526 @default.
- W3195991010 doi "https://doi.org/10.1021/acs.macromol.1c01111" @default.
- W3195991010 hasPublicationYear "2021" @default.
- W3195991010 type Work @default.
- W3195991010 sameAs 3195991010 @default.
- W3195991010 citedByCount "8" @default.