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• W3196013458 endingPage "13449" @default.
• W3196013458 startingPage "13441" @default.
• W3196013458 abstract "Visible-light-induced cycloaddition reactions initiated via energy-transfer processes have recently evolved as powerful methods for the construction of strained cyclic molecules that are not easily accessed using known ground-state synthetic methods. Particularly, the reactions initiated by the excitation of aromatic rings provide an alternative solution to the direct transformations of aromatic feedstocks under the scheme of dearomatization. Vinylcyclopropanes (VCPs) are well-known reagents in radical clock experiments, working as a probe to detect transient radical intermediates. However, the synthetic applications in this regard still remain limited due to uncontrollable selectivities. Herein, we report visible-light-induced dearomatization of indole- or pyrrole-tethered VCPs, in which several competitive reaction pathways, including [5 + 2], [2 + 2], interrupted [5 + 2], and [5 + 4] cycloadditions, can be well regulated by engineering substrate structures and tuning reaction conditions. The reaction mechanism has been explored by combined experimental and computational investigations. These reactions provide a convenient method to synthesize structurally diverse polycyclic molecules with high efficiency and good selectivity." @default.
• W3196013458 created "2021-08-30" @default.
• W3196013458 creator A5003028582 @default.
• W3196013458 creator A5006272093 @default.
• W3196013458 creator A5019588728 @default.
• W3196013458 creator A5064536916 @default.
• W3196013458 creator A5077105583 @default.
• W3196013458 date "2021-08-16" @default.
• W3196013458 modified "2023-09-30" @default.
• W3196013458 title "Visible-Light-Induced Dearomatization of Indoles/Pyrroles with Vinylcyclopropanes: Expedient Synthesis of Structurally Diverse Polycyclic Indolines/Pyrrolines" @default.
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