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- W3196092977 abstract "Xanthones are compounds with a diphenyl ether skeleton mainly found in plants and often glycosylated at carbon atoms. Although many C-glycosyltransferases (CGTs) participating in flavone C-glycosylation have been identified, MiCGT from Mangifera indica, adding sugar to an open-chain benzophenone skeleton, is the only identified xanthone biosynthesis-related CGT. Here, we identified two CGTs from Hypericum perforatum that add sugar to the closed-ring xanthone, but not benzophenone. These CGTs catalyze sugar transfer to the C-4 position of norathyriol (1,3,6,7-tetrahydroxyxanthone) to form isomangiferin (1,3,6,7-tetrahydroxyxanthone 4-C-glucoside), a major xanthone C-glucoside. This is the first study to report CGTs that mediate the direct C-glycosylation of xanthone." @default.
- W3196092977 created "2021-08-30" @default.
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- W3196092977 date "2021-08-24" @default.
- W3196092977 modified "2023-10-17" @default.
- W3196092977 title "Identification and characterization of glycosyltransferases catalyzing direct xanthone 4‐<i>C</i>‐glycosylation in <i>Hypericum perforatum</i>" @default.
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- W3196092977 doi "https://doi.org/10.1002/1873-3468.14179" @default.
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