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• W3196103654 startingPage "8969" @default.
• W3196103654 abstract "An unprecedented electrochemical heterodifunctionalization of α-CF3 alkenes with benzenesulfonyl hydrazides was accomplished in this work, wherein a β-sulfonyl and a α-hydroxyl group were simultaneously incorporated across the olefinic double bond in a single operation. Consequently, a series of potentially medicinally valuable and densely functionalized α-trifluoromethyl-β-sulfonyl tertiary alcohols were assembled under mild conditions. Electrochemically-driven oxidative 1,2-difunctionlization of electron-deficient alkenes well obviates the need for oxidizing reagents, thus rendering this protocol more eco-friendly." @default.
• W3196103654 created "2021-08-30" @default.
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• W3196103654 date "2021-01-01" @default.
• W3196103654 modified "2023-10-16" @default.
• W3196103654 title "Electrochemical heterodifunctionalization of α-CF₃ alkenes to access α-trifluoromethyl-β-sulfonyl tertiary alcohols" @default.
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• W3196103654 doi "https://doi.org/10.1039/d1cc03288g" @default.
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