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- W3196351362 abstract "The concise synthesis of dysifragilones A and B and dysidavarones has been accomplished for the first time in a divergent way from a common intermediate. The synthetic route features an intramolecular reductive Heck reaction to construct the 6/5/6/6/-tetracycle of dysifragilones A and B and an intramolecular palladium-catalyzed α-arylation of a sterically hindered ketone to forge the tetracyclo[7.7.1.02,7.010,15]heptadecane core structure of dysidavarone C. The late-stage introduction of amino and ethoxy groups is effective." @default.
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- W3196351362 date "2021-08-30" @default.
- W3196351362 modified "2023-09-29" @default.
- W3196351362 title "Total Synthesis of Dysifragilones A and B and Dysidavarone C" @default.
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- W3196351362 doi "https://doi.org/10.1021/acs.orglett.1c02641" @default.
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