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- W3196897341 abstract "Upon stabilization by 5,6-bis(diisopropylphosphino)acenaphthene to form compound 1, the fugitive antimony (I) cation exhibited nucleophilic behavior towards coinage metals. Compound 1 was strategically synthesized at room temperature from SbCl3 , the bis(phosphine), and trimethylsilyl trifluoromethanesulfonate taken in a 1:2:3 ratio, whereby the bis(phosphine) plays the dual role of a reductant and a supporting ligand. The generation of 1 involves two-electron oxidation of the ligand to form a P-P bonded diphosphonium dication. Compound 1 was separated from this dication to give both products in pure form in moderate yields. Despite the overall positive charge, the SbI site in 1 was found to bind to metal centers, forming complexes with AuI , AgI and CuI . Compound 1 reduced CuII to CuI and formed a coordination complex with the resulting CuI species. The effects of the electron-rich bis(phosphine) and the constrained peri geometry in stabilizing and enhancing the nucleophilicity of 1 have been rationalized through computational studies." @default.
- W3196897341 created "2021-09-13" @default.
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- W3196897341 creator A5072518846 @default.
- W3196897341 creator A5074071322 @default.
- W3196897341 creator A5078937085 @default.
- W3196897341 date "2021-10-22" @default.
- W3196897341 modified "2023-09-26" @default.
- W3196897341 title "Stabilization of the Elusive Antimony(I) Cation and Its Coordination Complexes with Transition Metals" @default.
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- W3196897341 doi "https://doi.org/10.1002/anie.202111339" @default.
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- W3196897341 hasPublicationYear "2021" @default.
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