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- W3197090411 abstract "5,15-bis(1-hydoxy-2,6-di-tert-butyl-phenyl)10,20-bis-(pentaphenyl-phenyl)phenyl porphyrin and its Nickel complex were synthesized. Oxidation with NOBF4 gave 5,15bis(1-oxo-2,6-ditertairy-butyl-phenyl)10,20-bis(pentaphenyl-phenyl)phenyl-porphodimethene and Ni bis(1-oxo-2,6-ditertairy-butyl-phenyl)10,20-bis-(pentaphenylphenyl)phenyl porphodimethene. The porphyrin conjugates were characterized by NMR, mass, and UV–visible spectroscopy for structural elucidation. The density functional theory studies revealed a decrease in the highest occupied and the lowest unoccupied molecular orbital (HOMO-LUMO) energy gaps in the oxo-porphodimethenes. The photochromism and fluorescence characteristics were also studied. The porphyrin moieties were found to be desirable for the reversible light-driven fluorescent molecular switches." @default.
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- W3197090411 date "2022-01-01" @default.
- W3197090411 modified "2023-10-12" @default.
- W3197090411 title "Synthesis of fluorescent molecular switches based on porphyrinoids covalently linked with redox active ligands" @default.
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- W3197090411 doi "https://doi.org/10.1016/j.molstruc.2021.131407" @default.
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