Matches in SemOpenAlex for { <https://semopenalex.org/work/W3197133081> ?p ?o ?g. }
- W3197133081 endingPage "44903" @default.
- W3197133081 startingPage "44893" @default.
- W3197133081 abstract "Most research on polymer composites has focused on adding discrete inorganic nanofillers to a polymer matrix to impart properties not found in polymers alone. However, properties such as ion conductivity and mechanical reinforcement would be greatly improved if the composite exhibited an interconnected network of inorganic and polymer phases. Here, we fabricate bicontinuous polymer-infiltrated scaffold metal (PrISM) composites by infiltrating polymer into nanoporous gold (NPG) films. Polystyrene (PS) and poly(2-vinylpyridine) (P2VP) films are infiltrated into the ∼43 nm diameter NPG pores via capillary forces during thermal annealing above the polymer glass transition temperature (Tg). The infiltration process is characterized in situ using spectroscopic ellipsometry. PS and P2VP, which have different affinities for the metal scaffold, exhibit slower segmental dynamics compared to their bulk counterparts when confined within the nanopores, as measured through Tg. The more attractive P2VP shows a 20 °C increase in Tg relative to its bulk, while PS only shows a 6 °C increase at a comparable molecular weight. The infiltrated polymer, in turn, stabilizes the gold nanopores against temporal coarsening. The broad tunability of these polymer/metal hybrids represents a unique template for designing functional network composite structures with applications ranging from flexible electronics to fuel cell membranes." @default.
- W3197133081 created "2021-09-13" @default.
- W3197133081 creator A5001320174 @default.
- W3197133081 creator A5030663793 @default.
- W3197133081 creator A5038571349 @default.
- W3197133081 creator A5058822275 @default.
- W3197133081 creator A5074582280 @default.
- W3197133081 creator A5076133429 @default.
- W3197133081 creator A5083901497 @default.
- W3197133081 creator A5085987305 @default.
- W3197133081 creator A5088670364 @default.
- W3197133081 date "2021-09-08" @default.
- W3197133081 modified "2023-10-16" @default.
- W3197133081 title "Effect of Nanoscale Confinement on Polymer-Infiltrated Scaffold Metal Composites" @default.
- W3197133081 cites W1566643221 @default.
- W3197133081 cites W1883449737 @default.
- W3197133081 cites W1965888702 @default.
- W3197133081 cites W1968241924 @default.
- W3197133081 cites W1969779099 @default.
- W3197133081 cites W1978983577 @default.
- W3197133081 cites W1990069173 @default.
- W3197133081 cites W1993927479 @default.
- W3197133081 cites W1998423081 @default.
- W3197133081 cites W1998644448 @default.
- W3197133081 cites W2000485513 @default.
- W3197133081 cites W2008151211 @default.
- W3197133081 cites W2008342341 @default.
- W3197133081 cites W2013106361 @default.
- W3197133081 cites W2014106979 @default.
- W3197133081 cites W2015945537 @default.
- W3197133081 cites W2032727309 @default.
- W3197133081 cites W2039204353 @default.
- W3197133081 cites W2042773037 @default.
- W3197133081 cites W2043485501 @default.
- W3197133081 cites W2044250060 @default.
- W3197133081 cites W2045437636 @default.
- W3197133081 cites W2047944375 @default.
- W3197133081 cites W2047973915 @default.
- W3197133081 cites W2050828857 @default.
- W3197133081 cites W2051045206 @default.
- W3197133081 cites W2051111574 @default.
- W3197133081 cites W2058238690 @default.
- W3197133081 cites W2060209458 @default.
- W3197133081 cites W2060293457 @default.
- W3197133081 cites W2061197763 @default.
- W3197133081 cites W2065946790 @default.
- W3197133081 cites W2072376902 @default.
- W3197133081 cites W2075430727 @default.
- W3197133081 cites W2077138067 @default.
- W3197133081 cites W2081203715 @default.
- W3197133081 cites W2081860981 @default.
- W3197133081 cites W2085824864 @default.
- W3197133081 cites W2087254943 @default.
- W3197133081 cites W2088519138 @default.
- W3197133081 cites W2094087621 @default.
- W3197133081 cites W2119183188 @default.
- W3197133081 cites W2119395741 @default.
- W3197133081 cites W2138827731 @default.
- W3197133081 cites W2139668087 @default.
- W3197133081 cites W2147355922 @default.
- W3197133081 cites W2156624199 @default.
- W3197133081 cites W2161943529 @default.
- W3197133081 cites W2170948389 @default.
- W3197133081 cites W2179142566 @default.
- W3197133081 cites W2191613790 @default.
- W3197133081 cites W2241003382 @default.
- W3197133081 cites W2273008578 @default.
- W3197133081 cites W2313793833 @default.
- W3197133081 cites W2314294626 @default.
- W3197133081 cites W2320201399 @default.
- W3197133081 cites W2324975076 @default.
- W3197133081 cites W2329494556 @default.
- W3197133081 cites W2332174861 @default.
- W3197133081 cites W2426399835 @default.
- W3197133081 cites W2527195098 @default.
- W3197133081 cites W2588725125 @default.
- W3197133081 cites W2598560680 @default.
- W3197133081 cites W2603668971 @default.
- W3197133081 cites W2755323378 @default.
- W3197133081 cites W2775044395 @default.
- W3197133081 cites W2783731228 @default.
- W3197133081 cites W2789088428 @default.
- W3197133081 cites W2800307313 @default.
- W3197133081 cites W2804863490 @default.
- W3197133081 cites W2810487970 @default.
- W3197133081 cites W2911990903 @default.
- W3197133081 cites W2914092099 @default.
- W3197133081 cites W2918292899 @default.
- W3197133081 cites W2944312887 @default.
- W3197133081 cites W2946113115 @default.
- W3197133081 cites W2954004025 @default.
- W3197133081 cites W2968765785 @default.
- W3197133081 cites W2981960315 @default.
- W3197133081 cites W2995807560 @default.
- W3197133081 cites W3012229946 @default.
- W3197133081 cites W3089703538 @default.
- W3197133081 cites W3097635333 @default.
- W3197133081 cites W3126442662 @default.