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• W3197142747 endingPage "2369" @default.
• W3197142747 startingPage "2351" @default.
• W3197142747 abstract "When substrates are confined in an isolated cavity, they experience circumstances that are distinctly different from those in a bulk solution. Molecular self-assembly has widened the potential of molecular confinement by offering synthetic cavities on the nanometer-scale and allowing chemists to treat molecular aggregates and larger molecules in the cavities. In this account, we introduce the molecular confinement effects of self-assembled cages as a strategy to discover new or hidden properties and reactivities from the confined substrates in the cages. By confining molecules, the cavity can gather, arrange, fold, compress, and twist the molecules. The molecular confinement thus becomes a powerful strategy to draw new aspects of molecules. The chemistry of molecular confinement has been extremely spread as chemists can treat molecular aggregates and larger molecules within large cavities of self-assembled hosts. In this account, we introduce the molecular confinement effects of our self-assembled cages as the phenomena in which new properties of molecules emerge in the chemically defined cavities." @default.
• W3197142747 created "2021-09-13" @default.
• W3197142747 creator A5019559729 @default.
• W3197142747 creator A5043413653 @default.
• W3197142747 date "2021-10-15" @default.
• W3197142747 modified "2023-10-11" @default.
• W3197142747 title "Molecular Confinement Effects by Self-Assembled Coordination Cages" @default.
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