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- W3197196132 abstract "Products from an iodine-mediated diallylsilane rearrangement were taken into an asymmetric dihydroxylation (AD) reaction resulting in the formation of diastereomeric 6-membered oxasilacycles. Removal of the epimeric stereocenter among this mixture of diastereomers by elimination of iodine produced a single enantioenriched cyclic allyl silyl ether. The resulting allyl silane was then successfully engaged in several further transformations, providing an alternative means to prepare useful intermediates for enantioselective synthesis." @default.
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- W3197196132 date "2021-10-01" @default.
- W3197196132 modified "2023-09-27" @default.
- W3197196132 title "Sequential iodine-mediated diallylsilane rearrangement/asymmetric dihydroxylation: Synthesis and reactions of enantioenriched oxasilacycles" @default.
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- W3197196132 doi "https://doi.org/10.1016/j.tetlet.2021.153392" @default.
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