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- W3197249411 abstract "In this study, the photosensitive nature of reactive enamine and polyenamine intermediates is investigated to improve our understanding of light-mediated aminocatalytic reactions. Experimental optical absorption data and TD-DFT calculations reveal that these intermediates are excited directly from the HOMO on the enamine moiety to low-lying unoccupied orbitals localized on the catalyst scaffold. This indicates that the photophysical properties of enamine intermediates can be tuned for visible light-mediated reactions by modifications to the aminocatalyst." @default.
- W3197249411 created "2021-09-13" @default.
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- W3197249411 date "2021-08-31" @default.
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- W3197249411 title "The Tunable Photophysical Properties of Enamine Intermediates Involved in Light-Driven Aminocatalysis" @default.
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- W3197249411 doi "https://doi.org/10.1021/acs.orglett.1c02387" @default.
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