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- W3197617230 startingPage "107175" @default.
- W3197617230 abstract "The structural and morphological changes occurred during the molten salt treatment of ilmenite (FeTiO3) are investigated by a variety of techniques including X-ray diffraction, scanning and transmission electron microscopy, as well as Raman and photoelectron spectroscopy. The phase evolution of ilmenite in molten LiCl under humid atmosphere leads to the facile formation of Li-containing phases such as Li0.8Ti2.2O4 and LiFeO2. Moreover, graphene nanosheets are successfully incorporated in the molten salt produced material through ball milling, and the Li-storage performance of the electrode made of the hybrid material is investigated. Unlike ilmenite, the hybrid structure exhibit an excellent electrochemical performance with a stable capacity of around 300 mAh g−1 after 500 successive discharge/charge cycles. This enhanced electrochemical performance is attributed to the presence of lithium oxide in the molten salt product that reduces the overall volume changes taking place during the lithiation/delithiation of the material, increasing the structural stability of the electrode. Furthermore, the presence of graphene nanosheets not only provides the electrical conductivity for the electrode, but also contributes to the structural stability of electrode by agglomerating the nanoparticles formed during cycling of the electrode. This article suggests a green and low-cost approach for the facile conversion of ilmenite into materials applicable for energy storage systems." @default.
- W3197617230 created "2021-09-13" @default.
- W3197617230 creator A5048101049 @default.
- W3197617230 creator A5087777101 @default.
- W3197617230 date "2021-10-01" @default.
- W3197617230 modified "2023-09-24" @default.
- W3197617230 title "Reactive molten salt modification of ilmenite as a green approach for the preparation of inexpensive Li ion battery anode materials" @default.
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- W3197617230 doi "https://doi.org/10.1016/j.mineng.2021.107175" @default.
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