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• W3197692528 abstract "A three-component thioamination reaction has been developed in the presence of phenyliodonium(III) diacetate (PIDA) leading to the formation of a thioaminated products. This catalytic approach represents a method for the metal-free thioamination of 1,4-naphthoquinone. It was observed that maleimides also work smoothly under this metal-free reaction condition. This present method implies the oxidative coupling reaction through a one-step process with the generation of C−N and C−S bonds. Various aromatic and aliphatic thiols and amines provided the corresponding thioaminated compounds in 62–88% yields. A plausible reaction pathway has been predicted according to few control experiments." @default.
• W3197692528 created "2021-09-13" @default.
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• W3197692528 date "2021-09-29" @default.
• W3197692528 modified "2023-09-30" @default.
• W3197692528 title "Metal‐Free, PhI(OAc) ₂ ‐Promoted Oxidative C( <i>sp</i> ^<i>2</i> )−H Difunctionalization: Synthesis of Thioaminated Naphthoquinones" @default.
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• W3197692528 doi "https://doi.org/10.1002/adsc.202100796" @default.
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