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- W3197771458 abstract "A formal method for C−H bond functionalization of amines with Michael acceptors and β-fluorinated gem-diols via α-aminoalkyl radicals generated using organic photoredox catalysis is reported. Under transition-metal free conditions, the α-aminoalkyl radicals are produced by dicyanopyrazine-derived photocatalyst through single electron transfer and subsequent deprotonation of C−H bonds, then the functionalized products are formed through later addition of generated radicals to electron-deficient alkenes. This work demonstrates the synthetic utilization of α-aminoalkyl radicals and photoredox potential of dicyanopyrazine-derived chromophore as a photocatalyst." @default.
- W3197771458 created "2021-09-13" @default.
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- W3197771458 date "2021-10-08" @default.
- W3197771458 modified "2023-10-18" @default.
- W3197771458 title "Dicyanopyrazine‐derived Chromophore as An Efficient Photocatalyst for α‐amino C‐H Bond Functionalization" @default.
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- W3197771458 doi "https://doi.org/10.1002/ajoc.202100467" @default.
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