Matches in SemOpenAlex for { <https://semopenalex.org/work/W3197874588> ?p ?o ?g. }
- W3197874588 endingPage "115461" @default.
- W3197874588 startingPage "115461" @default.
- W3197874588 abstract "We report the synthesis and characterization of a structurally-related series of iron-thiocarbonyl and methyl-functionalized iron-thiocarbyne complexes. Strategies towards the conversion of these species to a terminal iron carbide are also discussed. The remarkable catalytic transformation of CO to liquid hydrocarbons by Fe and Co catalysts in the industrial Fischer-Tropsch process motivates interest in developing well-defined systems to model aspects of this chemistry. One of the most interesting potential intermediates in this chemistry is a terminally-bound, first row metal carbide, yet a molecular model of this species remains elusive. With this in mind, we targeted the synthesis of highly-activated Fe-thiocarbonyl complexes, as prospective precursors to S-functionalization, C–S bond cleavage, and carbide generation. Herein, we describe the synthesis of three Fe–CS complexes that can be alkylated to generate a series of terminal Fe-carbynes that could be characterized across three oxidation states. Strategies to access C–S bond scission from these species are discussed, including limitations that, thus far, have precluded the generation of a terminal Fe-carbide for this system." @default.
- W3197874588 created "2021-09-13" @default.
- W3197874588 creator A5018743126 @default.
- W3197874588 creator A5057055428 @default.
- W3197874588 date "2021-11-01" @default.
- W3197874588 modified "2023-09-27" @default.
- W3197874588 title "Synthesis and functionalization reactivity of Fe-thiocarbonyl and thiocarbyne complexes" @default.
- W3197874588 cites W1479896687 @default.
- W3197874588 cites W1965148336 @default.
- W3197874588 cites W1968218061 @default.
- W3197874588 cites W1969065970 @default.
- W3197874588 cites W1970286415 @default.
- W3197874588 cites W1972382873 @default.
- W3197874588 cites W1977940043 @default.
- W3197874588 cites W1979795446 @default.
- W3197874588 cites W1981469476 @default.
- W3197874588 cites W1985658364 @default.
- W3197874588 cites W1986486029 @default.
- W3197874588 cites W1992816885 @default.
- W3197874588 cites W1997091718 @default.
- W3197874588 cites W2002115308 @default.
- W3197874588 cites W2002530972 @default.
- W3197874588 cites W2004738006 @default.
- W3197874588 cites W2007522509 @default.
- W3197874588 cites W2009545768 @default.
- W3197874588 cites W2012018675 @default.
- W3197874588 cites W2013498890 @default.
- W3197874588 cites W2013666102 @default.
- W3197874588 cites W2021059000 @default.
- W3197874588 cites W2023300210 @default.
- W3197874588 cites W2028939564 @default.
- W3197874588 cites W2031236542 @default.
- W3197874588 cites W2032484677 @default.
- W3197874588 cites W2035971487 @default.
- W3197874588 cites W2039315559 @default.
- W3197874588 cites W2046109895 @default.
- W3197874588 cites W2047246306 @default.
- W3197874588 cites W2050443665 @default.
- W3197874588 cites W2053257748 @default.
- W3197874588 cites W2063445402 @default.
- W3197874588 cites W2064922942 @default.
- W3197874588 cites W2066829750 @default.
- W3197874588 cites W2068520544 @default.
- W3197874588 cites W2073245799 @default.
- W3197874588 cites W2074267818 @default.
- W3197874588 cites W2075072091 @default.
- W3197874588 cites W2080678257 @default.
- W3197874588 cites W2081416838 @default.
- W3197874588 cites W2086790161 @default.
- W3197874588 cites W2091122982 @default.
- W3197874588 cites W2092136882 @default.
- W3197874588 cites W2095029118 @default.
- W3197874588 cites W2095123416 @default.
- W3197874588 cites W2096388739 @default.
- W3197874588 cites W2102479047 @default.
- W3197874588 cites W2105485926 @default.
- W3197874588 cites W2131073880 @default.
- W3197874588 cites W2139789686 @default.
- W3197874588 cites W2144241517 @default.
- W3197874588 cites W2145657661 @default.
- W3197874588 cites W2159684616 @default.
- W3197874588 cites W2170307999 @default.
- W3197874588 cites W2172182171 @default.
- W3197874588 cites W2212537533 @default.
- W3197874588 cites W2226279316 @default.
- W3197874588 cites W2294036243 @default.
- W3197874588 cites W2333903044 @default.
- W3197874588 cites W2399691098 @default.
- W3197874588 cites W2517614490 @default.
- W3197874588 cites W2546111401 @default.
- W3197874588 cites W2549581823 @default.
- W3197874588 cites W2581170820 @default.
- W3197874588 cites W2584870467 @default.
- W3197874588 cites W2584940556 @default.
- W3197874588 cites W2729798274 @default.
- W3197874588 cites W2757275283 @default.
- W3197874588 cites W2757890639 @default.
- W3197874588 cites W2762020843 @default.
- W3197874588 cites W2776744713 @default.
- W3197874588 cites W2789485297 @default.
- W3197874588 cites W2808662256 @default.
- W3197874588 cites W2810016863 @default.
- W3197874588 cites W2810090067 @default.
- W3197874588 cites W2913458039 @default.
- W3197874588 cites W2937785929 @default.
- W3197874588 cites W2942823436 @default.
- W3197874588 cites W2950458203 @default.
- W3197874588 cites W2952796992 @default.
- W3197874588 cites W2956119699 @default.
- W3197874588 cites W2969629539 @default.
- W3197874588 cites W2971739987 @default.
- W3197874588 cites W3000453056 @default.
- W3197874588 cites W3005449172 @default.
- W3197874588 cites W3023965626 @default.
- W3197874588 cites W47578210 @default.
- W3197874588 doi "https://doi.org/10.1016/j.poly.2021.115461" @default.
- W3197874588 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35910489" @default.
- W3197874588 hasPublicationYear "2021" @default.