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• W3197946418 startingPage "3170" @default.
• W3197946418 abstract "To optimize the factors affecting the generation and stability of [M(L)][Cp′3YII] complexes (Cp′ = C5H4SiMe3), reductions of Cp′3YIII with nine different combinations of alkali metals (M = Li, Na, K, Rb, Cs) and chelating agents (L = 2.2.2-cryptand, 18-crown-6, and dibenzo-18-crown-6) have been examined. The thermal decomposition of each [M(L)][Cp′3YII] product in THF at room temperature was monitored via UV–vis spectra collected over time, and the decomposition profiles were compared. The most stable M/L combination was found to be [K(crypt)][Cp′3YII] with a decomposition t1/2 ≈ 71 ± 7 min at an 80 mM concentration. The reduction reaction that generates [K(18-crown-6)][Cp′3YII] can be cleanly reversed by addition of Hg to generate the starting materials, Cp′3YIII and 18-crown-6, and potassium mercury amalgam." @default.
• W3197946418 created "2021-09-13" @default.
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• W3197946418 date "2021-09-03" @default.
• W3197946418 modified "2023-10-16" @default.
• W3197946418 title "Optimizing Alkali Metal (M) and Chelate (L) Combinations for the Synthesis and Stability of [M(L)][(C₅H₄SiMe₃)₃Y] Yttrium(II) Complexes" @default.
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• W3197946418 doi "https://doi.org/10.1021/acs.organomet.1c00379" @default.
• W3197946418 hasPublicationYear "2021" @default.
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