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- W3198215501 abstract "The enantioselective 1,2-reduction of α,β-unsaturated ketones has been achieved using a chiral pincer Mn catalyst. A series of PNN tridentate ligands containing benzimidazole groups were designed with ferrocene as the backbone, which coordinated with Mn to form the active catalyst. This mild process represents a general method to access chiral allyl alcohols with high catalytic activity (up to 9500 TON) and high enantioselectivity (66–86% ee). Furthermore, this catalytic system provides a novel synthesis of key pharmaceutical intermediates of cannabidiol." @default.
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- W3198215501 date "2021-10-01" @default.
- W3198215501 modified "2023-10-16" @default.
- W3198215501 title "Manganese catalyzed enantio- and regioselective hydrogenation of α,β-unsaturated ketones using an imidazole-based chiral PNN tridentate ligand" @default.
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- W3198215501 doi "https://doi.org/10.1016/j.tetlet.2021.153389" @default.
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