Matches in SemOpenAlex for { <https://semopenalex.org/work/W3198300510> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W3198300510 endingPage "1959" @default.
- W3198300510 startingPage "1956" @default.
- W3198300510 abstract "This paper describes the syntheses of four types of nitrile N-oxides (NOs) and studies on the thermal isomerization of NOs to isocyanates (Isocs). It is found that a bulky electron-withdrawing substituent at the ortho position of NO tends to suppress the thermal degradation of NO. The reaction rates for the thermal reactions appear to be dependent on the initial concentration. The reaction orders are analyzed in order to understand the reaction mechanism for the isomerization. It is indicated that the isomerization of NO could proceed via a reversible formation of polymeric intermediate. Thermal isomerizations of nitrile N-oxides to isocyanates are systematically investigated to clarify the substituent effects on the reaction rate. The reaction rates appear to be dependent on the reaction concentration, indicating the formation of polymeric intermediate for the isomerization." @default.
- W3198300510 created "2021-09-13" @default.
- W3198300510 creator A5017354594 @default.
- W3198300510 creator A5022766491 @default.
- W3198300510 creator A5050453724 @default.
- W3198300510 creator A5056423418 @default.
- W3198300510 creator A5059766717 @default.
- W3198300510 creator A5060982208 @default.
- W3198300510 creator A5079576473 @default.
- W3198300510 date "2021-12-05" @default.
- W3198300510 modified "2023-09-30" @default.
- W3198300510 title "Steric and Electronic Effects on Thermal Stability of Nitrile <i>N</i>-Oxide: a Case Study of Naphthalen-2-ol Derived Substrates" @default.
- W3198300510 cites W1963675818 @default.
- W3198300510 cites W1984983794 @default.
- W3198300510 cites W2009992004 @default.
- W3198300510 cites W2011975260 @default.
- W3198300510 cites W2023412782 @default.
- W3198300510 cites W2040143558 @default.
- W3198300510 cites W2044199573 @default.
- W3198300510 cites W2046554991 @default.
- W3198300510 cites W2061200634 @default.
- W3198300510 cites W2144591535 @default.
- W3198300510 cites W2282245169 @default.
- W3198300510 cites W2300738911 @default.
- W3198300510 cites W2331187108 @default.
- W3198300510 cites W2527649972 @default.
- W3198300510 cites W2660478160 @default.
- W3198300510 cites W2906839743 @default.
- W3198300510 cites W2973731785 @default.
- W3198300510 cites W2975535181 @default.
- W3198300510 cites W3008276084 @default.
- W3198300510 cites W3011216956 @default.
- W3198300510 cites W3085591349 @default.
- W3198300510 cites W3103189515 @default.
- W3198300510 cites W3159000749 @default.
- W3198300510 cites W4206764225 @default.
- W3198300510 doi "https://doi.org/10.1246/cl.210427" @default.
- W3198300510 hasPublicationYear "2021" @default.
- W3198300510 type Work @default.
- W3198300510 sameAs 3198300510 @default.
- W3198300510 citedByCount "1" @default.
- W3198300510 countsByYear W31983005102022 @default.
- W3198300510 crossrefType "journal-article" @default.
- W3198300510 hasAuthorship W3198300510A5017354594 @default.
- W3198300510 hasAuthorship W3198300510A5022766491 @default.
- W3198300510 hasAuthorship W3198300510A5050453724 @default.
- W3198300510 hasAuthorship W3198300510A5056423418 @default.
- W3198300510 hasAuthorship W3198300510A5059766717 @default.
- W3198300510 hasAuthorship W3198300510A5060982208 @default.
- W3198300510 hasAuthorship W3198300510A5079576473 @default.
- W3198300510 hasConcept C126661725 @default.
- W3198300510 hasConcept C155647269 @default.
- W3198300510 hasConcept C161790260 @default.
- W3198300510 hasConcept C178790620 @default.
- W3198300510 hasConcept C185592680 @default.
- W3198300510 hasConcept C201194858 @default.
- W3198300510 hasConcept C2778689049 @default.
- W3198300510 hasConcept C2779240715 @default.
- W3198300510 hasConcept C2779851234 @default.
- W3198300510 hasConcept C41339378 @default.
- W3198300510 hasConcept C59061564 @default.
- W3198300510 hasConcept C65024703 @default.
- W3198300510 hasConcept C75473681 @default.
- W3198300510 hasConceptScore W3198300510C126661725 @default.
- W3198300510 hasConceptScore W3198300510C155647269 @default.
- W3198300510 hasConceptScore W3198300510C161790260 @default.
- W3198300510 hasConceptScore W3198300510C178790620 @default.
- W3198300510 hasConceptScore W3198300510C185592680 @default.
- W3198300510 hasConceptScore W3198300510C201194858 @default.
- W3198300510 hasConceptScore W3198300510C2778689049 @default.
- W3198300510 hasConceptScore W3198300510C2779240715 @default.
- W3198300510 hasConceptScore W3198300510C2779851234 @default.
- W3198300510 hasConceptScore W3198300510C41339378 @default.
- W3198300510 hasConceptScore W3198300510C59061564 @default.
- W3198300510 hasConceptScore W3198300510C65024703 @default.
- W3198300510 hasConceptScore W3198300510C75473681 @default.
- W3198300510 hasIssue "12" @default.
- W3198300510 hasLocation W31983005101 @default.
- W3198300510 hasOpenAccess W3198300510 @default.
- W3198300510 hasPrimaryLocation W31983005101 @default.
- W3198300510 hasRelatedWork W1992400043 @default.
- W3198300510 hasRelatedWork W1998557180 @default.
- W3198300510 hasRelatedWork W2030215506 @default.
- W3198300510 hasRelatedWork W2063700760 @default.
- W3198300510 hasRelatedWork W2087764230 @default.
- W3198300510 hasRelatedWork W2089039237 @default.
- W3198300510 hasRelatedWork W2334320562 @default.
- W3198300510 hasRelatedWork W2973102837 @default.
- W3198300510 hasRelatedWork W3043663768 @default.
- W3198300510 hasRelatedWork W3198300510 @default.
- W3198300510 hasVolume "50" @default.
- W3198300510 isParatext "false" @default.
- W3198300510 isRetracted "false" @default.
- W3198300510 magId "3198300510" @default.
- W3198300510 workType "article" @default.