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- W3198406400 abstract "A novel lanthanide double-decker complex with nickel metallacrowns (MCs) as coordinating ligands has been synthesized. In the 3d/4f metallacrown complex TbIII[12-MCNiIIN(shi)-4]2, the central lanthanide ion is sandwiched between two [12-MC-4] units, forming an almost ideal square-antiprismatic coordination sphere. The resulting zenithal angles at the central lanthanide ion are smaller than those for previously reported sandwich compounds. Magnetic measurements reveal an energy barrier of 346 K under zero field and up to 585 K under 3200 Oe, the highest reported for metallacrowns with D4d symmetry." @default.
- W3198406400 created "2021-09-13" @default.
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- W3198406400 date "2021-08-31" @default.
- W3198406400 modified "2023-10-01" @default.
- W3198406400 title "3d/4f Sandwich Complex Based on Metallacrowns" @default.
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- W3198406400 doi "https://doi.org/10.1021/acs.inorgchem.1c01356" @default.
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