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- W3198501122 endingPage "122065" @default.
- W3198501122 startingPage "122065" @default.
- W3198501122 abstract "Symmetrical dirhodium(II) tetracarboxylate complexes bearing ferrocene-based supporting ligands in the axial positions, viz. [Rh2(CH3CO2)4L2] (1-3), where L = (diphenylphosphino)ferrocene (1), cyanoferrocene (2), and isocyanoferrocene (3), were prepared from [Rh2(CH3CO2)4] and the respective ferrocene derivative in ethanol. These complexes were structurally characterised by spectroscopic methods, single-crystal X-ray diffraction analysis and cyclic voltammetry. Our results showed that while compounds 1 and 3 are stable in both solid state and solution (complex 1 is very poorly soluble), the nitrile complex 2 easily decomposes through the loss of the isocyanide ligands." @default.
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- W3198501122 date "2021-11-01" @default.
- W3198501122 modified "2023-10-09" @default.
- W3198501122 title "Synthesis and characterisation of dirhodium(II) tetraacetates bearing axial ferrocene ligands" @default.
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- W3198501122 doi "https://doi.org/10.1016/j.jorganchem.2021.122065" @default.
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