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- W3198617354 abstract "For the functional enhancement on metal ion chelation, macroreticular copolymer beads were prepared by suspension polymerization of styrene, methylmethacrylate and divinylbenzene in the presence of a diluent. Accordingly, the carboxylic ester groups of copolymer beads were chloromethylated after hydroxymethylated in advance, whereas the phenyl ring of copolymer beads were directly chloromethylated. An indirect method for the conversion of chloromethylated groups to thiol groups consisted of treatment with thiourea to give an isothiuronium salt, which with alkali was cleaved to the mercaptan. Then, the thiol groups could be directly bound to carbon atoms in the showed high adsoption capacity for mercury ions. Also, the resin with benzene spacer units for thiol groups was highly effective for the adsorption of mercury ions:P when the thiol groups were utilized as a chelator heavy metal ions, it was very available to consider spacer effects among the groups on metal ion chelation." @default.
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- W3198617354 date "2002-01-01" @default.
- W3198617354 modified "2023-09-23" @default.
- W3198617354 title "2PB-5 : Adsorptivity toward heavy metal ions of chelating resins with thiol groups" @default.
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