FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3198769264> ?p ?o ?g. }

• W3198769264 endingPage "5488" @default.
• W3198769264 startingPage "5488" @default.
• W3198769264 abstract "Raman spectroscopy is a label-free, non-destructive, non-invasive analytical tool that provides insight into the molecular composition of samples with minimum or no sample preparation. The increased availability of commercial portable Raman devices presents a potentially easy and convenient analytical solution for day-to-day analysis in laboratories and production lines. However, their performance for highly specific and sensitive analysis applications has not been extensively evaluated. This study performs a direct comparison of such a commercially available, portable Raman system, with a research grade Raman microscope system for the analysis of water content of Natural Deep Eutectic Solvents (NADES). NADES are renewable, biodegradable and easily tunable “green” solvents, outcompeting existing organic solvents for applications in extraction from biomass, biocatalysis, and nanoparticle synthesis. Water content in NADES is, however, a critical parameter, affecting their properties, optimal use and extraction efficiency. In the present study, portable Raman spectroscopy coupled with Partial Least Squares Regression (PLSR) is investigated for rapid determination of water content in NADES samples in situ, i.e., directly in glassware. Three NADES systems, namely Betaine Glycerol (BG), Choline Chloride Glycerol (CCG) and Glucose Glycerol (GG), containing a range of water concentrations between 0% (w/w) and 28.5% (w/w), were studied. The results are directly compared with previously published studies of the same systems, using a research grade Raman microscope. PLSR results demonstrate the reliability of the analysis, surrendering R2 values above 0.99. Root Mean Square Errors Prediction (RMSEP) of 0.6805%, 0.9859% and 1.2907% w/w were found for respectively unknown CCG, BG and GG samples using the portable device compared to 0.4715%, 0.3437% and 0.7409% w/w previously obtained by analysis in quartz cuvettes with a Raman confocal microscope. Despite the relatively higher values of RMSEP observed, the comparison of the percentage of relative errors in the predicted concentration highlights that, overall, the portable device delivers accuracy below 5%. Ultimately, it has been demonstrated that portable Raman spectroscopy enables accurate quantification of water in NADES directly through glass vials without the requirement for sample withdrawal. Such compact instruments provide solvent and consumable free analysis for rapid analysis directly in laboratories and for non-expert users. Portable Raman is a promising approach for high throughput monitoring of water content in NADES that can support the development of new analytical protocols in the field of green chemistry in research and development laboratories but also in the industry as a routine quality control tool." @default.
• W3198769264 created "2021-09-13" @default.
• W3198769264 creator A5009418810 @default.
• W3198769264 creator A5014166958 @default.
• W3198769264 creator A5039831408 @default.
• W3198769264 creator A5046164453 @default.
• W3198769264 creator A5046543770 @default.
• W3198769264 creator A5073229240 @default.
• W3198769264 creator A5079930094 @default.
• W3198769264 creator A5082379967 @default.
• W3198769264 creator A5087201228 @default.
• W3198769264 creator A5088474921 @default.
• W3198769264 date "2021-09-09" @default.
• W3198769264 modified "2023-09-26" @default.
• W3198769264 title "In Situ Water Quantification in Natural Deep Eutectic Solvents Using Portable Raman Spectroscopy" @default.
• W3198769264 cites W1563946068 @default.
• W3198769264 cites W1964568311 @default.
• W3198769264 cites W1966554473 @default.
• W3198769264 cites W1974522943 @default.
• W3198769264 cites W1977538017 @default.
• W3198769264 cites W1980851776 @default.
• W3198769264 cites W1986076957 @default.
• W3198769264 cites W1988163389 @default.
• W3198769264 cites W1999842665 @default.
• W3198769264 cites W2004768162 @default.
• W3198769264 cites W2018373534 @default.
• W3198769264 cites W2018405026 @default.
• W3198769264 cites W2022072094 @default.
• W3198769264 cites W2024136278 @default.
• W3198769264 cites W2024490142 @default.
• W3198769264 cites W2027409735 @default.
• W3198769264 cites W2027678358 @default.
• W3198769264 cites W2032986759 @default.
• W3198769264 cites W2036206077 @default.
• W3198769264 cites W2047365824 @default.
• W3198769264 cites W2048629761 @default.
• W3198769264 cites W2051158233 @default.
• W3198769264 cites W2055201132 @default.
• W3198769264 cites W2059128138 @default.
• W3198769264 cites W2081033287 @default.
• W3198769264 cites W2081182951 @default.
• W3198769264 cites W2084489585 @default.
• W3198769264 cites W2087228475 @default.
• W3198769264 cites W2088642458 @default.
• W3198769264 cites W2089771516 @default.
• W3198769264 cites W2104970719 @default.
• W3198769264 cites W2126238127 @default.
• W3198769264 cites W2133790246 @default.
• W3198769264 cites W2140262998 @default.
• W3198769264 cites W2145211847 @default.
• W3198769264 cites W2148518515 @default.
• W3198769264 cites W2161988201 @default.
• W3198769264 cites W2295097024 @default.
• W3198769264 cites W2321586691 @default.
• W3198769264 cites W2346508965 @default.
• W3198769264 cites W2374663727 @default.
• W3198769264 cites W2400562535 @default.
• W3198769264 cites W2560115698 @default.
• W3198769264 cites W2594891638 @default.
• W3198769264 cites W2607259091 @default.
• W3198769264 cites W2724626715 @default.
• W3198769264 cites W2756949688 @default.
• W3198769264 cites W2789815678 @default.
• W3198769264 cites W2804566451 @default.
• W3198769264 cites W2811416308 @default.
• W3198769264 cites W2883843539 @default.
• W3198769264 cites W2886101218 @default.
• W3198769264 cites W2895418494 @default.
• W3198769264 cites W2902477017 @default.
• W3198769264 cites W2903010892 @default.
• W3198769264 cites W2903440427 @default.
• W3198769264 cites W2904976839 @default.
• W3198769264 cites W2905529905 @default.
• W3198769264 cites W2911487745 @default.
• W3198769264 cites W2921016893 @default.
• W3198769264 cites W2938659371 @default.
• W3198769264 cites W2947995705 @default.
• W3198769264 cites W2969209526 @default.
• W3198769264 cites W2971545555 @default.
• W3198769264 cites W3000509337 @default.
• W3198769264 cites W3007169283 @default.
• W3198769264 cites W3008974834 @default.
• W3198769264 cites W3025154776 @default.
• W3198769264 cites W3034905641 @default.
• W3198769264 cites W3036738774 @default.
• W3198769264 cites W3041736515 @default.
• W3198769264 cites W3042754945 @default.
• W3198769264 cites W3103705590 @default.
• W3198769264 cites W3119564243 @default.
• W3198769264 cites W3128119547 @default.
• W3198769264 cites W3147977953 @default.
• W3198769264 cites W3157471620 @default.
• W3198769264 cites W3165769994 @default.
• W3198769264 cites W826309317 @default.
• W3198769264 doi "https://doi.org/10.3390/molecules26185488" @default.
• W3198769264 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8471915" @default.
• W3198769264 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34576961" @default.
• W3198769264 hasPublicationYear "2021" @default.

• next