FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3198771645> ?p ?o ?g. }

• W3198771645 endingPage "14186" @default.
• W3198771645 startingPage "14176" @default.
• W3198771645 abstract "A nanometer sized solid solution of NiO and Al2O3 was synthesized by calcination of Ni-Al layered double hydroxides (LDHs). The crystal structure of the obtained compound was determined by XRD and XAFS analyses: Ni2+ and Al3+ ions are located at the metal ion site of the rock salt structure and a certain amount of cation vacancies are also introduced for charge compensation. The electrochemical properties of the Ni-Al binary metal oxide as an anode material for lithium ion batteries were examined by the constant current charge-discharge test. Ni-Al oxide showed higher charging capacity in comparison with pristine NiO. In particular, the capacity in the lower voltage region (below 1.5 V), the limited capacity in this region is the weak point of the conversion anode, was improved to 540 mA h g-1 that is about twice that of pristine NiO. This improvement in the capacity in the lower voltage region is concluded to be due to the redox activity of Al3+ ions during the charge-discharge on the basis of the results of electrochemical measurements and ex situ XAFS measurements at the Ni and Al edge. The reaction mechanism of this compound is investigated using ex situ XRD and XAFS methods. For the charge (reduction) in the higher voltage region (OCV-1.0 V), lithium ion intercalation into the cation vacancy sites and/or lithium ion adsorption on the surface of particles are proceeding. For the charge in the lower voltage region (1.0-0.03 V), conversion reaction occurs by the reduction of Ni2+ and Al3+ ions to metal particles with surface electrolyte interface (SEI) layer formation. For the discharge in the lower voltage region (0.03-1.5 V), only Al metal particles are oxidized to Al3+ ions and some intermediate complexes are formed. For the discharge in the higher voltage region (1.5-3.0 V), the lattice of the Ni-Al binary oxide solid solution is reconstructed with the oxidation of Ni to Ni2+." @default.
• W3198771645 created "2021-09-13" @default.
• W3198771645 creator A5001288691 @default.
• W3198771645 creator A5002751538 @default.
• W3198771645 creator A5006459161 @default.
• W3198771645 creator A5029312102 @default.
• W3198771645 creator A5037847790 @default.
• W3198771645 creator A5076351001 @default.
• W3198771645 creator A5082656506 @default.
• W3198771645 date "2021-01-01" @default.
• W3198771645 modified "2023-09-26" @default.
• W3198771645 title "Structure and Reaction Mechanism of Binary Ni-Al Oxides as Materials for Lithium-Ion Battery Anodes" @default.
• W3198771645 cites W1626854854 @default.
• W3198771645 cites W1966277940 @default.
• W3198771645 cites W1970835400 @default.
• W3198771645 cites W1978325934 @default.
• W3198771645 cites W1978450379 @default.
• W3198771645 cites W1979325119 @default.
• W3198771645 cites W1986525949 @default.
• W3198771645 cites W1987452691 @default.
• W3198771645 cites W1992375084 @default.
• W3198771645 cites W2003959091 @default.
• W3198771645 cites W2006243872 @default.
• W3198771645 cites W2016730434 @default.
• W3198771645 cites W2026419764 @default.
• W3198771645 cites W2040024770 @default.
• W3198771645 cites W2040915519 @default.
• W3198771645 cites W2042463871 @default.
• W3198771645 cites W2042490528 @default.
• W3198771645 cites W2043214618 @default.
• W3198771645 cites W2060063560 @default.
• W3198771645 cites W2072303327 @default.
• W3198771645 cites W2073751755 @default.
• W3198771645 cites W2076197537 @default.
• W3198771645 cites W2087512768 @default.
• W3198771645 cites W2095201883 @default.
• W3198771645 cites W2129584943 @default.
• W3198771645 cites W2138285500 @default.
• W3198771645 cites W2139664242 @default.
• W3198771645 cites W2312714773 @default.
• W3198771645 cites W2313492702 @default.
• W3198771645 cites W2987603913 @default.
• W3198771645 doi "https://doi.org/10.1039/d1dt01911b" @default.
• W3198771645 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34549737" @default.
• W3198771645 hasPublicationYear "2021" @default.
• W3198771645 type Work @default.
• W3198771645 sameAs 3198771645 @default.
• W3198771645 citedByCount "1" @default.
• W3198771645 countsByYear W31987716452023 @default.
• W3198771645 crossrefType "journal-article" @default.
• W3198771645 hasAuthorship W3198771645A5001288691 @default.
• W3198771645 hasAuthorship W3198771645A5002751538 @default.
• W3198771645 hasAuthorship W3198771645A5006459161 @default.
• W3198771645 hasAuthorship W3198771645A5029312102 @default.
• W3198771645 hasAuthorship W3198771645A5037847790 @default.
• W3198771645 hasAuthorship W3198771645A5076351001 @default.
• W3198771645 hasAuthorship W3198771645A5082656506 @default.
• W3198771645 hasConcept C113196181 @default.
• W3198771645 hasConcept C121332964 @default.
• W3198771645 hasConcept C134018914 @default.
• W3198771645 hasConcept C145148216 @default.
• W3198771645 hasConcept C147789679 @default.
• W3198771645 hasConcept C150244406 @default.
• W3198771645 hasConcept C161790260 @default.
• W3198771645 hasConcept C163258240 @default.
• W3198771645 hasConcept C17525397 @default.
• W3198771645 hasConcept C178790620 @default.
• W3198771645 hasConcept C179104552 @default.
• W3198771645 hasConcept C185592680 @default.
• W3198771645 hasConcept C191897082 @default.
• W3198771645 hasConcept C192562407 @default.
• W3198771645 hasConcept C2778541603 @default.
• W3198771645 hasConcept C2779197387 @default.
• W3198771645 hasConcept C2779851234 @default.
• W3198771645 hasConcept C32891209 @default.
• W3198771645 hasConcept C43617362 @default.
• W3198771645 hasConcept C52859227 @default.
• W3198771645 hasConcept C55493867 @default.
• W3198771645 hasConcept C555008776 @default.
• W3198771645 hasConcept C62520636 @default.
• W3198771645 hasConcept C71924100 @default.
• W3198771645 hasConcept C74575197 @default.
• W3198771645 hasConcept C89395315 @default.
• W3198771645 hasConceptScore W3198771645C113196181 @default.
• W3198771645 hasConceptScore W3198771645C121332964 @default.
• W3198771645 hasConceptScore W3198771645C134018914 @default.
• W3198771645 hasConceptScore W3198771645C145148216 @default.
• W3198771645 hasConceptScore W3198771645C147789679 @default.
• W3198771645 hasConceptScore W3198771645C150244406 @default.
• W3198771645 hasConceptScore W3198771645C161790260 @default.
• W3198771645 hasConceptScore W3198771645C163258240 @default.
• W3198771645 hasConceptScore W3198771645C17525397 @default.
• W3198771645 hasConceptScore W3198771645C178790620 @default.
• W3198771645 hasConceptScore W3198771645C179104552 @default.
• W3198771645 hasConceptScore W3198771645C185592680 @default.
• W3198771645 hasConceptScore W3198771645C191897082 @default.
• W3198771645 hasConceptScore W3198771645C192562407 @default.
• W3198771645 hasConceptScore W3198771645C2778541603 @default.

• next