FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3198867821> ?p ?o ?g. }

• W3198867821 endingPage "13010" @default.
• W3198867821 startingPage "13001" @default.
• W3198867821 abstract "The synthesis of calix[4]- and -[6]arene derivatives P6(H)22+·(Cl-)2, V4(H)24+·(Cl-)2·(I-)2, and V6(H)24+·(Cl-)2·(I-)2 bearing N-linked pyridinium (P) and viologen (V) units at the upper rim is described here. A rare example of an anionic conformational template is reported for p-pyridiniumcalix[6]arene P6(H)22+, which adopts a 1,3,5-alternate conformation in the presence of chloride anions. Derivatives P6(H)22+·(Cl-)2, V6(H)24+·(Cl-)2·(I-)2, and V4(H)24+·(Cl-)2·(I-)2 show a negative solvatochromism, while their UV-vis acid-base titration evidenced that upon addition of a base, new bands appear at 487, 583, and 686 nm, respectively, due to the formation of betainic monodeprotonated species P6(H)1+, V6(H)13+, and V4(H)13+. These new bands were attributable to the intramolecular charge-transfer (CT) transition from the phenoxide to the pyridinium or viologen moiety and were responsive to the presence of cations. In fact, the band at 487 nm of P6(H)1+ was quenched in the presence of a hard Li+ cation, and the color of its acetonitrile solution was changed from pink to colorless upon addition of LiI. Consequently, this derivative can be considered as a useful host for the recognition and sensing of lithium cations." @default.
• W3198867821 created "2021-09-13" @default.
• W3198867821 creator A5003888508 @default.
• W3198867821 creator A5017550000 @default.
• W3198867821 creator A5034467656 @default.
• W3198867821 creator A5059145730 @default.
• W3198867821 creator A5060643657 @default.
• W3198867821 creator A5061786566 @default.
• W3198867821 creator A5083583356 @default.
• W3198867821 creator A5091511715 @default.
• W3198867821 date "2021-09-01" @default.
• W3198867821 modified "2023-10-02" @default.
• W3198867821 title "Chromogenic Properties of <i>p</i>-Pyridinium- and <i>p</i>-Viologen-Calixarenes and Their Cation-Sensing Abilities" @default.
• W3198867821 cites W1414031722 @default.
• W3198867821 cites W1537337152 @default.
• W3198867821 cites W1593173232 @default.
• W3198867821 cites W1965686703 @default.
• W3198867821 cites W1973084533 @default.
• W3198867821 cites W1973540996 @default.
• W3198867821 cites W1975070783 @default.
• W3198867821 cites W1977752625 @default.
• W3198867821 cites W1979304333 @default.
• W3198867821 cites W1988079455 @default.
• W3198867821 cites W1991549024 @default.
• W3198867821 cites W1996273492 @default.
• W3198867821 cites W1999509593 @default.
• W3198867821 cites W1999955685 @default.
• W3198867821 cites W2003063198 @default.
• W3198867821 cites W2022497975 @default.
• W3198867821 cites W2025786467 @default.
• W3198867821 cites W2030936891 @default.
• W3198867821 cites W2032133327 @default.
• W3198867821 cites W2039686868 @default.
• W3198867821 cites W2039710330 @default.
• W3198867821 cites W2041794913 @default.
• W3198867821 cites W2051894048 @default.
• W3198867821 cites W2053422619 @default.
• W3198867821 cites W2054745620 @default.
• W3198867821 cites W2059254864 @default.
• W3198867821 cites W2059471388 @default.
• W3198867821 cites W2061480850 @default.
• W3198867821 cites W2063639336 @default.
• W3198867821 cites W2075592843 @default.
• W3198867821 cites W2079969050 @default.
• W3198867821 cites W2090391132 @default.
• W3198867821 cites W2098431552 @default.
• W3198867821 cites W2118705816 @default.
• W3198867821 cites W2146301009 @default.
• W3198867821 cites W2159056572 @default.
• W3198867821 cites W2321461470 @default.
• W3198867821 cites W2329379252 @default.
• W3198867821 cites W2515430482 @default.
• W3198867821 cites W2568046654 @default.
• W3198867821 cites W2598700181 @default.
• W3198867821 cites W2614263475 @default.
• W3198867821 cites W2616082673 @default.
• W3198867821 cites W2780711500 @default.
• W3198867821 cites W2789176227 @default.
• W3198867821 cites W2901133643 @default.
• W3198867821 cites W2925947457 @default.
• W3198867821 cites W2960157653 @default.
• W3198867821 cites W2968650759 @default.
• W3198867821 cites W2971717943 @default.
• W3198867821 cites W3005861989 @default.
• W3198867821 cites W3040986209 @default.
• W3198867821 cites W3084149672 @default.
• W3198867821 cites W3084424883 @default.
• W3198867821 cites W3091796044 @default.
• W3198867821 cites W3098736040 @default.
• W3198867821 cites W3101628710 @default.
• W3198867821 cites W4246198599 @default.
• W3198867821 doi "https://doi.org/10.1021/acs.joc.1c01687" @default.
• W3198867821 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8453632" @default.
• W3198867821 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34469156" @default.
• W3198867821 hasPublicationYear "2021" @default.
• W3198867821 type Work @default.
• W3198867821 sameAs 3198867821 @default.
• W3198867821 citedByCount "3" @default.
• W3198867821 countsByYear W31988678212022 @default.
• W3198867821 countsByYear W31988678212023 @default.
• W3198867821 crossrefType "journal-article" @default.
• W3198867821 hasAuthorship W3198867821A5003888508 @default.
• W3198867821 hasAuthorship W3198867821A5017550000 @default.
• W3198867821 hasAuthorship W3198867821A5034467656 @default.
• W3198867821 hasAuthorship W3198867821A5059145730 @default.
• W3198867821 hasAuthorship W3198867821A5060643657 @default.
• W3198867821 hasAuthorship W3198867821A5061786566 @default.
• W3198867821 hasAuthorship W3198867821A5083583356 @default.
• W3198867821 hasAuthorship W3198867821A5091511715 @default.
• W3198867821 hasBestOaLocation W31988678211 @default.
• W3198867821 hasConcept C115624301 @default.
• W3198867821 hasConcept C155647269 @default.
• W3198867821 hasConcept C178790620 @default.
• W3198867821 hasConcept C179104552 @default.
• W3198867821 hasConcept C184866935 @default.
• W3198867821 hasConcept C185592680 @default.
• W3198867821 hasConcept C2776568683 @default.
• W3198867821 hasConcept C2777221202 @default.

• next