Matches in SemOpenAlex for { <https://semopenalex.org/work/W3199572353> ?p ?o ?g. }
- W3199572353 endingPage "12869" @default.
- W3199572353 startingPage "12858" @default.
- W3199572353 abstract "Green pathways for nonisocyanate polyurethane (NIPU) production have attracted increasing levels of interest. The reaction between 5-membered cyclic carbonate and polyamines is one of the most promising pathways to produce NIPU polymers. Though promising, major technical hurdles such as slow polymerization rate and poor performance hinder the commercialization of NIPU. In this paper, we screened several commercially available triglyceride oil feedstocks for NIPU products, focusing on polymerization kinetics and product performance for industrial application. The impact of carbonated group density on polymerization rate and mechanical strength was determined. We have demonstrated a remarkably higher reactivity of carbonated oil derived from feedstocks with polyunsaturated fatty acid (PUFA). The NIPU derived from such feedstocks also showed improved performance for industrial application. Unlike traditional polyurethane foam production that uses isocyanate and water to generate CO2 as a blowing reagent, there is no gas formation in NIPU polymerization. We have demonstrated a practical and cost-effective approach to produce NIPU foam material using bicarbonate as a blowing reagent. Furthermore, we conducted the first-ever technoeconomic analysis (TEA), revealing that profitable commercial NIPU production can be achieved when operating at sufficient production capacities." @default.
- W3199572353 created "2021-09-27" @default.
- W3199572353 creator A5007198695 @default.
- W3199572353 creator A5053376788 @default.
- W3199572353 creator A5057408007 @default.
- W3199572353 creator A5073767834 @default.
- W3199572353 creator A5077655975 @default.
- W3199572353 creator A5078237557 @default.
- W3199572353 creator A5080693496 @default.
- W3199572353 date "2021-09-15" @default.
- W3199572353 modified "2023-10-04" @default.
- W3199572353 title "Assessment of Plant and Microalgal Oil-Derived Nonisocyanate Polyurethane Products for Potential Commercialization" @default.
- W3199572353 cites W1902113603 @default.
- W3199572353 cites W1971564151 @default.
- W3199572353 cites W1990573894 @default.
- W3199572353 cites W1992871983 @default.
- W3199572353 cites W1994161194 @default.
- W3199572353 cites W1997823367 @default.
- W3199572353 cites W1998197731 @default.
- W3199572353 cites W2002573779 @default.
- W3199572353 cites W2004514488 @default.
- W3199572353 cites W2007458920 @default.
- W3199572353 cites W2016619004 @default.
- W3199572353 cites W2038023276 @default.
- W3199572353 cites W2040851558 @default.
- W3199572353 cites W2047602927 @default.
- W3199572353 cites W2049147312 @default.
- W3199572353 cites W2073755851 @default.
- W3199572353 cites W2074188361 @default.
- W3199572353 cites W2100105319 @default.
- W3199572353 cites W2109475727 @default.
- W3199572353 cites W2135512249 @default.
- W3199572353 cites W2150206147 @default.
- W3199572353 cites W2168422917 @default.
- W3199572353 cites W2234354692 @default.
- W3199572353 cites W2254003811 @default.
- W3199572353 cites W2275809797 @default.
- W3199572353 cites W2285714628 @default.
- W3199572353 cites W2395993931 @default.
- W3199572353 cites W2414955279 @default.
- W3199572353 cites W2419572128 @default.
- W3199572353 cites W2442652975 @default.
- W3199572353 cites W2524766624 @default.
- W3199572353 cites W2556785912 @default.
- W3199572353 cites W2594146852 @default.
- W3199572353 cites W2618029199 @default.
- W3199572353 cites W2791593105 @default.
- W3199572353 cites W2796341395 @default.
- W3199572353 cites W2889749256 @default.
- W3199572353 cites W2914662150 @default.
- W3199572353 cites W2924054596 @default.
- W3199572353 cites W2944408871 @default.
- W3199572353 cites W2946723043 @default.
- W3199572353 cites W2984521099 @default.
- W3199572353 cites W3001413872 @default.
- W3199572353 cites W3006814567 @default.
- W3199572353 cites W3090505996 @default.
- W3199572353 cites W3123369258 @default.
- W3199572353 cites W3133117531 @default.
- W3199572353 cites W3134365872 @default.
- W3199572353 cites W3180084182 @default.
- W3199572353 doi "https://doi.org/10.1021/acssuschemeng.1c03653" @default.
- W3199572353 hasPublicationYear "2021" @default.
- W3199572353 type Work @default.
- W3199572353 sameAs 3199572353 @default.
- W3199572353 citedByCount "17" @default.
- W3199572353 countsByYear W31995723532022 @default.
- W3199572353 countsByYear W31995723532023 @default.
- W3199572353 crossrefType "journal-article" @default.
- W3199572353 hasAuthorship W3199572353A5007198695 @default.
- W3199572353 hasAuthorship W3199572353A5053376788 @default.
- W3199572353 hasAuthorship W3199572353A5057408007 @default.
- W3199572353 hasAuthorship W3199572353A5073767834 @default.
- W3199572353 hasAuthorship W3199572353A5077655975 @default.
- W3199572353 hasAuthorship W3199572353A5078237557 @default.
- W3199572353 hasAuthorship W3199572353A5080693496 @default.
- W3199572353 hasBestOaLocation W31995723533 @default.
- W3199572353 hasConcept C127413603 @default.
- W3199572353 hasConcept C144133560 @default.
- W3199572353 hasConcept C162853370 @default.
- W3199572353 hasConcept C178790620 @default.
- W3199572353 hasConcept C185592680 @default.
- W3199572353 hasConcept C192562407 @default.
- W3199572353 hasConcept C2779578285 @default.
- W3199572353 hasConcept C2780534471 @default.
- W3199572353 hasConcept C2780625559 @default.
- W3199572353 hasConcept C40875361 @default.
- W3199572353 hasConcept C42360764 @default.
- W3199572353 hasConcept C44228677 @default.
- W3199572353 hasConcept C521977710 @default.
- W3199572353 hasConcept C528095902 @default.
- W3199572353 hasConceptScore W3199572353C127413603 @default.
- W3199572353 hasConceptScore W3199572353C144133560 @default.
- W3199572353 hasConceptScore W3199572353C162853370 @default.
- W3199572353 hasConceptScore W3199572353C178790620 @default.
- W3199572353 hasConceptScore W3199572353C185592680 @default.
- W3199572353 hasConceptScore W3199572353C192562407 @default.
- W3199572353 hasConceptScore W3199572353C2779578285 @default.