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- W3199618439 abstract "A novel Ti–W–O-cluster-substituted tungstoantimonate (TA), [H2N(CH3)2]3Na4H9[{Ti6W4O18(OH)(H2O)3}(B-α-SbW9O33)3]·20H2O (1), has been made by hydrothermal reactions of trivacant [B-α-SbW9O33]9– units, Ti4+ cations, and WO42– anions in the presence of [H2N(CH3)2]·Cl and structurally characterized. Intriguingly, the polyoxoanion of 1 is constructed from three [B-α-SbW9O33]9– units and a previously unobserved decanuclear heterometallic Ti–W–O cluster [Ti6W4O18(OH)(H2O)3]11+ ({Ti6W4}) that is comprised of an octahedral [Ti6WO6(H2O)3]18+ cluster and an edge-sharing [W3O12(OH)]7– fragment via six W–O–Ti/W linkers. Furthermore, studies on the catalytic oxidation properties reveal that 1 possesses good catalytic activity toward the oxidation reactions of various sulfides and cyclooctene based on the environmentally friendly oxidant H2O2." @default.
- W3199618439 created "2021-09-27" @default.
- W3199618439 creator A5017805403 @default.
- W3199618439 creator A5022505566 @default.
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- W3199618439 date "2021-09-17" @default.
- W3199618439 modified "2023-09-24" @default.
- W3199618439 title "A {Ti<sub>6</sub>W<sub>4</sub>}-Cluster-Substituted Polyoxotungstate: Synthesis, Structure, and Catalytic Oxidation Properties" @default.
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- W3199618439 doi "https://doi.org/10.1021/acs.inorgchem.1c01643" @default.
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