Matches in SemOpenAlex for { <https://semopenalex.org/work/W3199701995> ?p ?o ?g. }
- W3199701995 endingPage "11109" @default.
- W3199701995 startingPage "11095" @default.
- W3199701995 abstract "Vector-borne diseases cause around 700,000 deaths every year. Insect repellents are one of the strategies to limit them. Para-menthane-3,8-diol (PMD), a natural compound, is one of the most promising alternatives to conventional synthetic repellents. This work describes a diastereodivergent method to synthesize each diastereoisomer of PMD from enantiopure citronellal and studies their repellence activity against Aedes albopictus. We found that cis-PMD is the kinetic control product of the cyclization of citronellal, while trans-PMD is the thermodynamic control product. X-ray diffraction analysis of crystals highlighted some differences in hydrogen-bond patterns between cis or trans isomers. The present paper demonstrates that (1R)-(+)-cis-PMD has the highest repellency index using a new evaluation system for 24 h. (1S)-(-)-cis-PMD has somewhat lower and (1S)-(+)-trans-PMD and (1R)-(-)-trans-PMD have a slight effect. Volunteer tests show that (1R)-(+)-cis-PMD is the most efficient. This effect could be ascribed to the interaction of PMD/insect odorant receptors and their physical properties, that is, the evaporation rate." @default.
- W3199701995 created "2021-09-27" @default.
- W3199701995 creator A5000269975 @default.
- W3199701995 creator A5001785925 @default.
- W3199701995 creator A5003822680 @default.
- W3199701995 creator A5006439263 @default.
- W3199701995 creator A5013299252 @default.
- W3199701995 creator A5039473771 @default.
- W3199701995 creator A5056850539 @default.
- W3199701995 date "2021-09-13" @default.
- W3199701995 modified "2023-09-25" @default.
- W3199701995 title "Effect of the Stereoselectivity of <i>para</i>-Menthane-3,8-diol Isomers on Repulsion toward <i>Aedes albopictus</i>" @default.
- W3199701995 cites W1566847801 @default.
- W3199701995 cites W1597808783 @default.
- W3199701995 cites W1964426836 @default.
- W3199701995 cites W1970643190 @default.
- W3199701995 cites W1999736917 @default.
- W3199701995 cites W2003286828 @default.
- W3199701995 cites W2007974136 @default.
- W3199701995 cites W2008556298 @default.
- W3199701995 cites W2012488984 @default.
- W3199701995 cites W2021253771 @default.
- W3199701995 cites W2021903377 @default.
- W3199701995 cites W2022856928 @default.
- W3199701995 cites W2030995957 @default.
- W3199701995 cites W2033885593 @default.
- W3199701995 cites W2052337437 @default.
- W3199701995 cites W2052773750 @default.
- W3199701995 cites W2053837454 @default.
- W3199701995 cites W2069535294 @default.
- W3199701995 cites W2071955309 @default.
- W3199701995 cites W2076928414 @default.
- W3199701995 cites W2077716593 @default.
- W3199701995 cites W2079338080 @default.
- W3199701995 cites W2082788644 @default.
- W3199701995 cites W2083297182 @default.
- W3199701995 cites W2089716902 @default.
- W3199701995 cites W2090764033 @default.
- W3199701995 cites W2092522608 @default.
- W3199701995 cites W2094989836 @default.
- W3199701995 cites W2095202132 @default.
- W3199701995 cites W2096790537 @default.
- W3199701995 cites W2102311681 @default.
- W3199701995 cites W2116448710 @default.
- W3199701995 cites W2127435093 @default.
- W3199701995 cites W2133610719 @default.
- W3199701995 cites W2138501896 @default.
- W3199701995 cites W2139770950 @default.
- W3199701995 cites W2140369871 @default.
- W3199701995 cites W2142568927 @default.
- W3199701995 cites W2144827811 @default.
- W3199701995 cites W2148902174 @default.
- W3199701995 cites W2153468003 @default.
- W3199701995 cites W2156071256 @default.
- W3199701995 cites W2163406441 @default.
- W3199701995 cites W2163645458 @default.
- W3199701995 cites W2166544014 @default.
- W3199701995 cites W2167713409 @default.
- W3199701995 cites W2173191568 @default.
- W3199701995 cites W2177619950 @default.
- W3199701995 cites W2179126167 @default.
- W3199701995 cites W2180980498 @default.
- W3199701995 cites W2196582507 @default.
- W3199701995 cites W2240223114 @default.
- W3199701995 cites W2323470410 @default.
- W3199701995 cites W2326910476 @default.
- W3199701995 cites W2333192041 @default.
- W3199701995 cites W2410450473 @default.
- W3199701995 cites W2582645770 @default.
- W3199701995 cites W2603348045 @default.
- W3199701995 cites W2772004151 @default.
- W3199701995 cites W2792435546 @default.
- W3199701995 cites W2886196843 @default.
- W3199701995 cites W2886375368 @default.
- W3199701995 cites W2887829890 @default.
- W3199701995 cites W2889764510 @default.
- W3199701995 cites W2899170997 @default.
- W3199701995 cites W2939872958 @default.
- W3199701995 cites W2951287221 @default.
- W3199701995 cites W3008543655 @default.
- W3199701995 cites W3172541016 @default.
- W3199701995 cites W4230848918 @default.
- W3199701995 cites W4230945270 @default.
- W3199701995 doi "https://doi.org/10.1021/acs.jafc.1c03897" @default.
- W3199701995 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34514794" @default.
- W3199701995 hasPublicationYear "2021" @default.
- W3199701995 type Work @default.
- W3199701995 sameAs 3199701995 @default.
- W3199701995 citedByCount "6" @default.
- W3199701995 countsByYear W31997019952021 @default.
- W3199701995 countsByYear W31997019952022 @default.
- W3199701995 countsByYear W31997019952023 @default.
- W3199701995 crossrefType "journal-article" @default.
- W3199701995 hasAuthorship W3199701995A5000269975 @default.
- W3199701995 hasAuthorship W3199701995A5001785925 @default.
- W3199701995 hasAuthorship W3199701995A5003822680 @default.
- W3199701995 hasAuthorship W3199701995A5006439263 @default.
- W3199701995 hasAuthorship W3199701995A5013299252 @default.