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- W31997367 endingPage "1396" @default.
- W31997367 startingPage "1386" @default.
- W31997367 abstract "The gas phase (1 atm, 453 K) hydrogenation of p-chloronitrobenzene (p-CNB) over a series of laboratory-synthesized and commercial Pd (1–10% wt) supported on activated carbon (AC) and non-reducible (SiO2 and Al2O3) and reducible (ZnO) oxides has been examined. Reaction over these catalysts generated the target p-chloroaniline (p-CAN) (via selective hydrogenation) and nitrobenzene (NB)/aniline (AN) as a result of a combined hydrodechlorination/hydrogenation. A range of Pd nanoparticles with mean sizes 2.4–12.6 nm (from HRTEM and H2/CO chemisorption) were generated. Both the p-CNB transformation rate and H2 chemisorption increased with decreasing Pd size. Residual Mo (from the stabilizer used in the synthesis of Pd colloids) suppressed activity, but this was circumvented by the use of poly(N-vinyl-2-pyrrolidone) (PVP). Pd/AC generated p-CAN and AN as principal products, Pd on SiO2 and Al2O3 exhibited hydrodechlorination character generating AN and NB, and Pd/ZnO promoted the sole formation of p-CAN at all le..." @default.
- W31997367 created "2016-06-24" @default.
- W31997367 creator A5005311112 @default.
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- W31997367 creator A5059736138 @default.
- W31997367 creator A5060128762 @default.
- W31997367 creator A5084291905 @default.
- W31997367 date "2013-05-22" @default.
- W31997367 modified "2023-10-01" @default.
- W31997367 title "Selective Gas Phase Hydrogenation of <i>p</i>-Chloronitrobenzene over Pd Catalysts: Role of the Support" @default.
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