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- W3199903638 endingPage "12374" @default.
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- W3199903638 abstract "An intermolecular enantioselective synthesis of 1H-isoindoles containing tri- and difluoromethylated quaternary stereogenic centers through a palladium-catalyzed desymmetric C–H bond imidoylation has been developed. α,α-Diaryl tri- and difluoroethylated isocyanides acted as powerful precursors of chiral 1H-isoindoles, in which the fluoroalkyl group was proven to play a crucial role in both the stereochemistry and reaction efficiency. In addition, an allene insertion cascade was realized, offering rapid access to diverse C1-tethered bis-heterocyclic scaffolds with good yields and high enantioselectivities. The reactions proceeded smoothly under mild conditions with low catalyst loadings." @default.
- W3199903638 created "2021-09-27" @default.
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- W3199903638 date "2021-09-22" @default.
- W3199903638 modified "2023-10-18" @default.
- W3199903638 title "Enantioselective Construction of 1<i>H</i>-Isoindoles Containing Tri- and Difluoromethylated Quaternary Stereogenic Centers via Palladium-Catalyzed C–H Bond Imidoylation" @default.
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