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- W3199954319 endingPage "11848" @default.
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- W3199954319 abstract "A copper-catalyzed asymmetric decarboxylative propargylic alkylation of enol carbonates has been realized, allowing for the highly stereoselective formation of acyclic vicinal tri- and tetrasubstituted stereocenters. With this strategy, a series of optically active quaternary α-amino acid esters with an adjunct chiral tertiary propargylic moiety have been prepared from propargyl azlactone-enol carbonates in high yields and with good to excellent diastereo- and enantioselectivities. The success of this reaction exemplifies the high potential of the decarboxylative strategy to resolve unmet challenges present in traditional catalytic propargylic alkylation." @default.
- W3199954319 created "2021-09-27" @default.
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- W3199954319 date "2021-09-09" @default.
- W3199954319 modified "2023-10-15" @default.
- W3199954319 title "Copper-Catalyzed Decarboxylative Propargylic Alkylation of Enol Carbonates: Stereoselective Synthesis of Quaternary α-Amino Acids" @default.
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- W3199954319 doi "https://doi.org/10.1021/acscatal.1c03421" @default.
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