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• W3199961511 abstract "• The successful synthesis of carbon quantum dots (CQDs) using sweet potato as a green source. • Fabrication of a sensitive and accurate fluorometric sensor to detect 6-mercaptopurine (6-MP) using the synthesized CQDs. • The deceloped sensor detected 6-MP in the concentration range of 0.4–5.4 mgL −1 with the LOD of 0.01 mgL −1 . • The recovery values of the spiked samples were in the range of 88–120% in real samples. 6-mercaptopurine (6-MP) is an anticancer drug used in the treatment of a variety of cancers. Regarding its wide application, rapid and accurate detection of 6-MP is of great interest. Conventional techniques have significant drawbacks such as complex sample preparation, time-consuming analysis, and being expensive. On the other hand, fluorometric sensors have been used vastly to detect various chemical and biological analytes. Hydrothermal technique synthesized carbon quantum dots (CQDs) using a facile and environmentally benign approach using sweet potato as the carbon source. It was observed that in the presence of the 6-MP drug, the fluorescence emission of CQDs was enhanced. At first, the effect of important parameters (pH, temperature, and the CQDs volume ratio) on the fluorescence emission intensity was studied. Then the fluorometric sensor was used to determine 6-MP in different concentration ranges and complex solutions. The developed sensor showed promising results for the determination of 6-MP in the linear range of 0.4–5.4 mg L −1 and the detection limit of 0.01 mg L −1 . The results were repeatable even in complex solutions in the presence of possible interfering species." @default.
• W3199961511 created "2021-09-27" @default.
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• W3199961511 date "2021-12-01" @default.
• W3199961511 modified "2023-10-17" @default.
• W3199961511 title "Green synthesis of carbon quantum dots and their application as a fluorometric sensor for highly selective determination of 6-mercaptopurine in biological samples" @default.
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• W3199961511 doi "https://doi.org/10.1016/j.jtice.2021.09.015" @default.
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