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- W3200357227 abstract "Dihydrogen Hδ+⋅⋅⋅Hδ− bonding that is accepted as an important unconventional hydrogen bonding could play a key role in molecular self-assembly of amine boranes. It is with this goal in mind that we have studied the behavior of n-dodecylamine borane nC12H25NH2BH3 (C12AB) dissolved in anhydrous THF. C12AB can be easily synthesized with a purity higher than 99% by Lewis acid-base reaction of a BH3 complex with n-dodecylamine nC12H25NH2. It is stable when dissolved in THF that is a good solvent of it. However, it is unstable in the presence of moisture, readily hydrolyzing and producing water-soluble borates. Molecular self-assembly of C12AB has thus to be studied in anhydrous conditions, which allows observing by DLS and SAXS-WAXS the formation of core-shell aggregates in anhydrous THF. The aggregates consist of about five self-assembling stretched C12AB molecules where the NH2BH3 groups are in the core of 3 Å and the alkyl chains in an outer-shell." @default.
- W3200357227 created "2021-09-27" @default.
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- W3200357227 date "2022-01-01" @default.
- W3200357227 modified "2023-10-07" @default.
- W3200357227 title "Synthesis of n-dodecylamine borane C12H25NH2BH3, its stability against hydrolysis, and its characterization in THF" @default.
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- W3200357227 doi "https://doi.org/10.1016/j.molstruc.2021.131484" @default.
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