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• W3200379120 endingPage "2819" @default.
• W3200379120 startingPage "2763" @default.
• W3200379120 abstract "Abstract Nature is incessantly affianced to construct bioactive and structurally intriguing compounds with magnificent three‐dimensional frameworks in the Universe. The inadequacy of these naturally occurring precious compounds prompted several minds of chemists to synthesise them in a laboratory for a thorough evaluation of their medicinal and clinical properties via a structure‐activity relationship study. Finding an optimised methodology to synthesise chiral natural products has always been challenging in synthetic organic chemistry, particularly the formation of asymmetric carbon‐carbon bonds adhering to the existing stereochemistry. In this context, chiral auxiliaries have proven to be effective tools for inducing chirality during the synthesis of chiral molecules. In fact, the chiral auxiliary will allow us to control the synthesis of many enantiomerically pure isomers in natural product synthesis. In this area, the significant contribution of the Evans’ chiral auxiliary in TiCl 4 ‐mediated asymmetric aldol reactions to the installation of known configurations in organic synthetic chemistry motivated us to compile an exhaustive and systematic summary of the relevant research findings published in the last two decades." @default.
• W3200379120 created "2021-09-27" @default.
• W3200379120 creator A5015358560 @default.
• W3200379120 creator A5021805477 @default.
• W3200379120 creator A5039069934 @default.
• W3200379120 date "2021-10-15" @default.
• W3200379120 modified "2023-10-17" @default.
• W3200379120 title "TiCl ₄ ‐Promoted Asymmetric Aldol Reaction of Oxazolidinones and its Sulphur‐Congeners for Natural Product Synthesis" @default.
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