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- W3200380974 endingPage "116898" @default.
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- W3200380974 abstract "Electrode potential stability is a major challenge for solid-contact ion-selective electrodes (SC-ISEs), with the formation of a water layer in the ion-to-electron transducer being the main cause of electrode potential instability. To investigate this problem, hydrophilic polyaniline (PANI) nanofibers doped with H3PO4 (PANI-H3PO4, water contact angle (CA) 48°) and highly hydrophobic polyaniline nanofibers doped with perfluorooctanoic acid (PANI-PFOA, CA 120°) were prepared by electrochemical deposition and secondary doping, then used as the solid contact layer in the construction of Pb2+-ISEs. By studying the potential response of the fabricated Pb2+-ISEs to Pb2+ ions using chronopotentiometry and water layer tests as a function time, it was determined that Pb2+-ISEs containing hydrophobic PANI-PFOA as the solid contact layer offered superior stability potential and a longer life. The potential drift of the developed GC/PANI-PFOA/Pb2+-ISM electrode was only 21.62 ± 4 μV/h, while the potential drift of GC/PANI-PFOA/Pb2+-ISM electrode was 197.6 ± 16 μV/h, highlighting the benefits of a strongly hydrophobic SC layer in SC-ISEs construction." @default.
- W3200380974 created "2021-09-27" @default.
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- W3200380974 date "2021-11-01" @default.
- W3200380974 modified "2023-10-14" @default.
- W3200380974 title "Potential stability improvement in Pb2+ ion selective electrodes by applying hydrophobic polyaniline as ion-to-electron transducer" @default.
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- W3200380974 doi "https://doi.org/10.1016/j.synthmet.2021.116898" @default.
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