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- W3200466970 abstract "The effects of substituting the B cation in A3BO7 ceramics on their thermal physical properties were investigated by applying a large mass difference. Y3(Nb1-xTax)O7 (x = 0, 0.1, 0.2, 0.3, 0.4, and 0.5) ceramics were synthesized, and their structural characteristics were determined. All the fabricated Y3(Nb1-xTax)O7 ceramics showed defective fluorite structures and glass-like low thermal conductivity (1.18−2.04 W/m∙K at 25°C) because of the highly distorted crystal structure and significant mass difference. Substitution with Ta5+ enhanced the sintering resistance, leading to superior thermal-insulating performance via grain boundary scattering. Furthermore, the ceramics exhibited excellent coefficients of thermal expansion, implying the promising applicability of Y3(Nb1-xTax)O7 as new thermal barrier materials. The effect of mass difference on the thermomechanical properties of the ceramics was examined, suggesting a simple strategy for engineering the chemical composition of new thermal barrier materials." @default.
- W3200466970 created "2021-09-27" @default.
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- W3200466970 date "2021-09-28" @default.
- W3200466970 modified "2023-09-27" @default.
- W3200466970 title "Effect of Ta <sup>5+</sup> doping on the thermal physical properties of defective fluorite Y <sub>3</sub> NbO <sub>7</sub> ceramics" @default.
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- W3200466970 doi "https://doi.org/10.1111/jace.18135" @default.
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