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• W3200499711 endingPage "256" @default.
• W3200499711 startingPage "203" @default.
• W3200499711 abstract "The use of inert CH bonds instead of traditional functional groups has great potentials to streamline modern organic synthesis with high atom- and step-economy, in which noble transition metal catalysis has played a predominant role so far. Despite the intriguing characteristics of manganese such as abundance in the Earth's crust, low toxicity, promising unprecedented reactivity, and so on, early efforts on manganese-mediated organometallic C–H activation were mainly limited to stoichiometric reactions. Recently, manganese-catalyzed organometallic C–H activation reactions have surged benefitting from new strategies to construct efficient catalytic cycles for manganese. In this chapter, recent explosive advances on manganese-catalyzed organometallic C–H activation are categorized into varied reactions of key manganacycle intermediates with a series of substrates from a mechanistic viewpoint. Both manganese carbonyl and non-carbonyl catalysts are covered and an outlook on this emerging field is also put forward." @default.
• W3200499711 created "2021-09-27" @default.
• W3200499711 creator A5008499728 @default.
• W3200499711 creator A5088018076 @default.
• W3200499711 date "2021-09-12" @default.
• W3200499711 modified "2023-10-16" @default.
• W3200499711 title "Manganese‐Catalyzed Organometallic <scp>C</scp>  <scp>H</scp> Activation" @default.
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