FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3200536008> ?p ?o ?g. }

• W3200536008 endingPage "14661" @default.
• W3200536008 startingPage "14653" @default.
• W3200536008 abstract "A series of rare earth biphenolate complexes of the general form [Ln(mbmp)(mbmpH)(thf)3] (Ln = Y (1), Nd (2), Gd (3), Dy (4), Er (5), Tm (6) and Lu (7)) have been synthesised by redox transmetallation/protolysis (RTP) from the free rare earth metal, Hg(C6F5)2 and 2,2'-methylenebis(6-tert-butyl-4-methylphenol) (mbmpH2). The rare earth metal is six coordinate with one chelating biphenolate mbmp2- ligand and one unidentate monophenolate mbmpH- ligand. The yttrium complex, when crystallised from hot toluene or deuterated benzene, loses a coordinated thf and exhibits coordination through all three phenolate oxygen atoms, as well as the oxygen of the phenol, yielding two solvates [Y(mbmp)(mbmpH)(thf)2]·nsolv (solv = PhMe, n = 1 (8a) or C6D6, n = 2 (8b)). Of these rare earth complexes, the yttrium derivative (1) yielded the heterobimetallic complex [AlMe2Y(mbmp)2(thf)2] (9) when treated with trimethylaluminium, whereas all other complexes produced the transmetallation product [AlMe(mbmp)(thf)] (11). The dinuclear dysprosium complex [Dy2(mbmp)3(thf)3] (10) was isolated alongside 11 from the reaction of 4 with trimethylaluminium, suggesting trimethylaluminium instigates a redistribution reaction. The ROP activity of the mononuclear neodymium, dysprosium, lutetium, and aluminium complexes towards rac-lactide in toluene at 70 °C was found to be poor compared to rare earth complexes of monodentate aryloxides, but increased with increased rare earth ion size." @default.
• W3200536008 created "2021-09-27" @default.
• W3200536008 creator A5022274278 @default.
• W3200536008 creator A5025850865 @default.
• W3200536008 creator A5042241049 @default.
• W3200536008 creator A5057799933 @default.
• W3200536008 creator A5064617775 @default.
• W3200536008 creator A5068029188 @default.
• W3200536008 creator A5070036826 @default.
• W3200536008 date "2021-01-01" @default.
• W3200536008 modified "2023-10-13" @default.
• W3200536008 title "New lanthanoid biphenolate complexes, their further reactivity with trimethylaluminium and catalytic activity for the polymerisation of <i>rac</i>-lactide" @default.
• W3200536008 cites W1968178051 @default.
• W3200536008 cites W1969360633 @default.
• W3200536008 cites W1983759499 @default.
• W3200536008 cites W1984772918 @default.
• W3200536008 cites W1985570466 @default.
• W3200536008 cites W1992441297 @default.
• W3200536008 cites W2013299343 @default.
• W3200536008 cites W2026931136 @default.
• W3200536008 cites W2034451952 @default.
• W3200536008 cites W2036968790 @default.
• W3200536008 cites W2047615243 @default.
• W3200536008 cites W2050674459 @default.
• W3200536008 cites W2052664824 @default.
• W3200536008 cites W2056188057 @default.
• W3200536008 cites W2057427048 @default.
• W3200536008 cites W2077773569 @default.
• W3200536008 cites W2078244979 @default.
• W3200536008 cites W2083282609 @default.
• W3200536008 cites W2083452662 @default.
• W3200536008 cites W2110035145 @default.
• W3200536008 cites W2125810639 @default.
• W3200536008 cites W2126203424 @default.
• W3200536008 cites W2129126650 @default.
• W3200536008 cites W2134008319 @default.
• W3200536008 cites W2139295359 @default.
• W3200536008 cites W2160466249 @default.
• W3200536008 cites W2163488189 @default.
• W3200536008 cites W2167590372 @default.
• W3200536008 cites W2170498612 @default.
• W3200536008 cites W2945837214 @default.
• W3200536008 cites W3016350788 @default.
• W3200536008 cites W2047035033 @default.
• W3200536008 doi "https://doi.org/10.1039/d1dt02513a" @default.
• W3200536008 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34585180" @default.
• W3200536008 hasPublicationYear "2021" @default.
• W3200536008 type Work @default.
• W3200536008 sameAs 3200536008 @default.
• W3200536008 citedByCount "4" @default.
• W3200536008 countsByYear W32005360082022 @default.
• W3200536008 countsByYear W32005360082023 @default.
• W3200536008 crossrefType "journal-article" @default.
• W3200536008 hasAuthorship W3200536008A5022274278 @default.
• W3200536008 hasAuthorship W3200536008A5025850865 @default.
• W3200536008 hasAuthorship W3200536008A5042241049 @default.
• W3200536008 hasAuthorship W3200536008A5057799933 @default.
• W3200536008 hasAuthorship W3200536008A5064617775 @default.
• W3200536008 hasAuthorship W3200536008A5068029188 @default.
• W3200536008 hasAuthorship W3200536008A5070036826 @default.
• W3200536008 hasConcept C116569031 @default.
• W3200536008 hasConcept C142653250 @default.
• W3200536008 hasConcept C142724271 @default.
• W3200536008 hasConcept C145148216 @default.
• W3200536008 hasConcept C155647269 @default.
• W3200536008 hasConcept C161790260 @default.
• W3200536008 hasConcept C170493617 @default.
• W3200536008 hasConcept C178516000 @default.
• W3200536008 hasConcept C178790620 @default.
• W3200536008 hasConcept C179104552 @default.
• W3200536008 hasConcept C185592680 @default.
• W3200536008 hasConcept C201770740 @default.
• W3200536008 hasConcept C204787440 @default.
• W3200536008 hasConcept C2776910235 @default.
• W3200536008 hasConcept C2779851234 @default.
• W3200536008 hasConcept C525727330 @default.
• W3200536008 hasConcept C531131001 @default.
• W3200536008 hasConcept C544153396 @default.
• W3200536008 hasConcept C55493867 @default.
• W3200536008 hasConcept C71924100 @default.
• W3200536008 hasConceptScore W3200536008C116569031 @default.
• W3200536008 hasConceptScore W3200536008C142653250 @default.
• W3200536008 hasConceptScore W3200536008C142724271 @default.
• W3200536008 hasConceptScore W3200536008C145148216 @default.
• W3200536008 hasConceptScore W3200536008C155647269 @default.
• W3200536008 hasConceptScore W3200536008C161790260 @default.
• W3200536008 hasConceptScore W3200536008C170493617 @default.
• W3200536008 hasConceptScore W3200536008C178516000 @default.
• W3200536008 hasConceptScore W3200536008C178790620 @default.
• W3200536008 hasConceptScore W3200536008C179104552 @default.
• W3200536008 hasConceptScore W3200536008C185592680 @default.
• W3200536008 hasConceptScore W3200536008C201770740 @default.
• W3200536008 hasConceptScore W3200536008C204787440 @default.
• W3200536008 hasConceptScore W3200536008C2776910235 @default.
• W3200536008 hasConceptScore W3200536008C2779851234 @default.
• W3200536008 hasConceptScore W3200536008C525727330 @default.
• W3200536008 hasConceptScore W3200536008C531131001 @default.
• W3200536008 hasConceptScore W3200536008C544153396 @default.

• next