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• W3200749968 startingPage "21169" @default.
• W3200749968 abstract "This research demonstrates the cation and anion transfer of an organic ionic plastic crystal (OIPC), quinuclidinium hexafluorophosphate ([HQ]PF6), in the pure state and mixtures doped with lithium or chloride ions. The pure material and the mixtures show relatively simple thermal behaviors. Powder X-ray diffraction determined a cubic crystal structure, a common feature of OIPCs, in the high-temperature phase of the pure material. Solid-state nuclear resonance spectra of the pure material reveal rotation-assisted ion mobility and the presence of the plastic crystal phase. The ionic conductivity of the mixtures doped with lithium ions and chloride ions increases significantly. Arrhenius conduction behaviors are observed in both the pure material and ion-doped mixtures, with effective activation energies of ∼60–110 kJ mol–1. Ionic conductivity also implies that ions transfer either through the bulk crystal or via grain boundaries. This is the first time that the cation and anion transfer in a quinuclidinium-based OIPC is reported, and the anion (here Cl–) is transferred in plastic crystal systems where solid solutions are likely formed. Different ion conduction behaviors of the pure and doped materials are closely associated with shapes and relative sizes of constituent ions. The results provide useful information to improve the understanding of structure–property relationships in OIPCs." @default.
• W3200749968 created "2021-09-27" @default.
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• W3200749968 date "2021-09-21" @default.
• W3200749968 modified "2023-10-17" @default.
• W3200749968 title "Cation and Anion Transfer in Quinuclidinium Hexafluorophosphate Plastic Crystal: Role of Constituent Ions and the Crystalline Structure" @default.
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• W3200749968 doi "https://doi.org/10.1021/acs.jpcc.1c05891" @default.
• W3200749968 hasPublicationYear "2021" @default.
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