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• W3200768008 endingPage "103424" @default.
• W3200768008 startingPage "103424" @default.
• W3200768008 abstract "Six novel lactamomethyl derivatives of 2,5-dimethylphenol and 2,3,5-trimethylphenol were prepared with moderate yields by the reaction of corresponding phenols with 1-(hydroxymethyl)lactams in the presence of an acid catalyst. In all cases, the substitution occurred at position 4 to the phenolic hydroxyl group. The structures of all synthesized compounds were confirmed by FT-IR, 1 H and 13 C NMR, 2D NMR and elemental analysis. The selectivity and possible pathways of the lactamomethylation reaction were studied by quantum-chemical methods. In silico calculations showed that the substitution at para -position to the hydroxyl group of the corresponding phenols was more preferable due to the higher stability of forming intermediates." @default.
• W3200768008 created "2021-09-27" @default.
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• W3200768008 date "2021-09-01" @default.
• W3200768008 modified "2023-09-24" @default.
• W3200768008 title "Lactamomethylation of alkylphenols: synthesis and quantum-chemical study of the reaction pathway" @default.
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• W3200768008 doi "https://doi.org/10.1016/j.arabjc.2021.103424" @default.
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