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• W3200909809 endingPage "5520" @default.
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• W3200909809 abstract "Halogen-bonded networks have been prepared by cocrystallization of the linear ditopic halogen bond donor diiodoacetylene C2I2 and lipophilic phosphonium salts of the octahedral hexatopic halogen bond acceptor hexacyanoferrate(III) [Fe(CN)6]3–. The crystal structure of [PPh3Me]3[Fe(CN)6]·3C2I2·7.5MeCN displays a two-fold interpenetrated, three-dimensional cubic halogen-bonded network, in which the C≡N···I angles are almost linear (170.4(4) and 167.6(4)°). In the case of [PPh4]3[Fe(CN)6]·4C2I2·6CH3CN, a two-dimensional ribbon structure with mono- and bifurcated acceptor sites is observed, while [PNP]3[Fe(CN)6]·4C2I2·4CH2Cl2 displays a three-dimensional halogen-bonded network structure. In the latter two structures, C≡N···I angles are in the range of 99.2(6)–161.8(6)° and 118.9(2)–143.1(2)°, respectively. This finding illustrates the high structural flexibility of C2I2 coordination to cyanide ligands, which is supposed to be a consequence of packing effects." @default.
• W3200909809 created "2021-09-27" @default.
• W3200909809 creator A5017869996 @default.
• W3200909809 creator A5024475665 @default.
• W3200909809 creator A5083391134 @default.
• W3200909809 date "2021-09-14" @default.
• W3200909809 modified "2023-10-09" @default.
• W3200909809 title "Cubic Three-Dimensional Networks of the Cyanometalate [Fe(CN)₆]³^– with the Ditopic Halogen Bond Donor Diiodoacetylene C₂I₂" @default.
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• W3200909809 doi "https://doi.org/10.1021/acs.cgd.1c00882" @default.
• W3200909809 hasPublicationYear "2021" @default.
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