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- W3200984860 endingPage "33" @default.
- W3200984860 startingPage "23" @default.
- W3200984860 abstract "TTF- and exTTF-containing [(μ-S2)Fe2(CO)6] complexes have been prepared by the photochemical reaction of TTF or exTTF and [(μ-S2)Fe2(CO)6]. These complexes are able to interact with PAHs. In the absence of air and in acid media an electrocatalytic dihydrogen evolution reaction (HER) occurs, similarly to analogous [(μ-S2)Fe2(CO)6] complexes. However, in the presence of air, the TTF and exTTF organic moieties strongly influence the electrochemistry of these systems. The reported data may be valuable in the design of [FeFe] hydrogenase mimics able to combine the HER properties of the [FeFe] cores with the unique TTF properties." @default.
- W3200984860 created "2021-09-27" @default.
- W3200984860 creator A5007664572 @default.
- W3200984860 creator A5011696529 @default.
- W3200984860 creator A5038290507 @default.
- W3200984860 creator A5048069564 @default.
- W3200984860 creator A5056174065 @default.
- W3200984860 date "2021-09-13" @default.
- W3200984860 modified "2023-10-12" @default.
- W3200984860 title "Electrocatalytic Behavior of Tetrathiafulvalene (TTF) and Extended Tetrathiafulvalene (exTTF) [FeFe] Hydrogenase Mimics" @default.
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- W3200984860 doi "https://doi.org/10.1021/acsorginorgau.1c00011" @default.
- W3200984860 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36855407" @default.