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- W3201020111 abstract "Metal-organic framework (MOF) thin films have recently attracted much attention as a new platform for surface/interface research, where unconventional structural and physical properties emerge. Among the many MOFs as candidates for fabrication of thin films, Hofmann-type MOFs {Fe(pz)[M(CN)4]} [pz = pyrazine; M = Ni (Nipz), M = Pt (Ptpz)] are attractive, because they undergo spin transitions with concomitant structural changes. Here, we demonstrate the first example of a strain-controlled spin transition in heterostructured MOF thin films. The spin transition temperature of Ptpz can be controlled in the temperature range of 300-380 K by fabricating a nanometer-sized heterostructured thin film with a Nipz buffer layer, where the smaller lattice of Nipz causes epitaxial compressive strain to the Ptpz layer. The fabricated heterostructured thin film exhibited a remarkable increase in spin transition temperature with a dynamic structural transformation, confirmed by variable-temperature (VT) X-ray diffraction and VT Raman spectroscopy. By verifying interfacial strain in a heterostructured thin film, we can rationally control the characteristics of MOFs-not only spin transition but also various physical properties such as gas storage, catalysis, sensing, proton conductivity, and electrical properties, among others." @default.
- W3201020111 created "2021-09-27" @default.
- W3201020111 creator A5005938410 @default.
- W3201020111 creator A5012966085 @default.
- W3201020111 creator A5036397249 @default.
- W3201020111 creator A5056389807 @default.
- W3201020111 creator A5057253611 @default.
- W3201020111 date "2021-09-13" @default.
- W3201020111 modified "2023-10-17" @default.
- W3201020111 title "Strain-Controlled Spin Transition in Heterostructured Metal–Organic Framework Thin Film" @default.
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- W3201020111 doi "https://doi.org/10.1021/jacs.1c06662" @default.
- W3201020111 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34514790" @default.
- W3201020111 hasPublicationYear "2021" @default.
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