FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3201064384> ?p ?o ?g. }

• W3201064384 endingPage "117337" @default.
• W3201064384 startingPage "117337" @default.
• W3201064384 abstract "Forming solid solutions between two isostructural compounds is an important strategy of regulating thermal transport in solids and boosting thermoelectric performance of narrow gap semiconductors. However, its full potential is not reached in a large variety of systems because of the known miscibility gap. A typical example includes PbS-PbTe where a limited solubility is demonstrated for one in another. Here in this study we show that the miscibility gap between PbS and PbTe is well bridged by introducing 30 mol% PbSe. This considerably extends the solubility limit of PbTe from only ∼4 mol% in PbS to at least 16 mol% in PbS0.7Se0.3, thus remarkably reducing the lattice thermal conductivity from a solid solution point of view. More importantly, it is found that carrier mobility of PbS is negligibly affected by this heavy alloying process, which is against conventional knowledge that higher concentration of defects leads to stronger carrier scattering. Our electron localization functions (ELF) mapping calculation results suggest an increased overlap of the adjacent electron clouds and decreased periodic potential fluctuations when the miscibility gap between PbS and PbTe gets bridged by PbSe. Therefore, the strengthened chemical bond covalency of PbS upon PbSe/PbTe alloying is responsible for the well reserved carrier mobilities. The simultaneous optimization of electron and phonon transport enabled by miscibility gap engineering (also applicable to many other technologically important thermoelectric materials) greatly boosts the thermoelectric performance of n-type Ga-doped PbS, leading to an excellent peak ZT of ∼1.1 at ∼723 K together with a record high average ZT value of 0.73 (300-723 K) in the samples of Pb0.99Ga0.01S0.7-xSe0.3Tex (x ≥ 0.12)." @default.
• W3201064384 created "2021-09-27" @default.
• W3201064384 creator A5008598564 @default.
• W3201064384 creator A5013105695 @default.
• W3201064384 creator A5016806564 @default.
• W3201064384 creator A5034894648 @default.
• W3201064384 creator A5048822014 @default.
• W3201064384 creator A5071037763 @default.
• W3201064384 creator A5082390639 @default.
• W3201064384 creator A5086682044 @default.
• W3201064384 date "2021-11-01" @default.
• W3201064384 modified "2023-10-18" @default.
• W3201064384 title "Bridging the miscibility gap towards higher thermoelectric performance of PbS" @default.
• W3201064384 cites W1905330982 @default.
• W3201064384 cites W1970127494 @default.
• W3201064384 cites W1979544533 @default.
• W3201064384 cites W1984285541 @default.
• W3201064384 cites W1990240535 @default.
• W3201064384 cites W1995952816 @default.
• W3201064384 cites W2001139162 @default.
• W3201064384 cites W2006512995 @default.
• W3201064384 cites W2007206010 @default.
• W3201064384 cites W2010196105 @default.
• W3201064384 cites W2020521333 @default.
• W3201064384 cites W2027314252 @default.
• W3201064384 cites W2029741576 @default.
• W3201064384 cites W2031056282 @default.
• W3201064384 cites W2041532378 @default.
• W3201064384 cites W2053820215 @default.
• W3201064384 cites W2055625159 @default.
• W3201064384 cites W2058771191 @default.
• W3201064384 cites W2065252673 @default.
• W3201064384 cites W2066013233 @default.
• W3201064384 cites W2075482120 @default.
• W3201064384 cites W2075937489 @default.
• W3201064384 cites W2080181778 @default.
• W3201064384 cites W2083222334 @default.
• W3201064384 cites W2086470851 @default.
• W3201064384 cites W2094972715 @default.
• W3201064384 cites W2102437645 @default.
• W3201064384 cites W2112425685 @default.
• W3201064384 cites W2131370539 @default.
• W3201064384 cites W2151592156 @default.
• W3201064384 cites W2154413093 @default.
• W3201064384 cites W2160689836 @default.
• W3201064384 cites W2161332314 @default.
• W3201064384 cites W2168367960 @default.
• W3201064384 cites W2198416647 @default.
• W3201064384 cites W2319344044 @default.
• W3201064384 cites W2506355356 @default.
• W3201064384 cites W2511197735 @default.
• W3201064384 cites W2626395583 @default.
• W3201064384 cites W2757598758 @default.
• W3201064384 cites W2758922007 @default.
• W3201064384 cites W2790852074 @default.
• W3201064384 cites W2790865346 @default.
• W3201064384 cites W2791708193 @default.
• W3201064384 cites W2804237232 @default.
• W3201064384 cites W2805603620 @default.
• W3201064384 cites W2889859665 @default.
• W3201064384 cites W2898430048 @default.
• W3201064384 cites W2904334276 @default.
• W3201064384 cites W2912762183 @default.
• W3201064384 cites W2928610785 @default.
• W3201064384 cites W2939550625 @default.
• W3201064384 cites W2955331224 @default.
• W3201064384 cites W2956069619 @default.
• W3201064384 cites W2975160810 @default.
• W3201064384 cites W2978452230 @default.
• W3201064384 cites W2979385599 @default.
• W3201064384 cites W2991204839 @default.
• W3201064384 cites W2999102631 @default.
• W3201064384 cites W3004556088 @default.
• W3201064384 cites W3010597605 @default.
• W3201064384 cites W3013707377 @default.
• W3201064384 cites W3022049444 @default.
• W3201064384 cites W3038217617 @default.
• W3201064384 cites W3083891673 @default.
• W3201064384 cites W3091305600 @default.
• W3201064384 cites W3138192836 @default.
• W3201064384 doi "https://doi.org/10.1016/j.actamat.2021.117337" @default.
• W3201064384 hasPublicationYear "2021" @default.
• W3201064384 type Work @default.
• W3201064384 sameAs 3201064384 @default.
• W3201064384 citedByCount "15" @default.
• W3201064384 countsByYear W32010643842022 @default.
• W3201064384 countsByYear W32010643842023 @default.
• W3201064384 crossrefType "journal-article" @default.
• W3201064384 hasAuthorship W3201064384A5008598564 @default.
• W3201064384 hasAuthorship W3201064384A5013105695 @default.
• W3201064384 hasAuthorship W3201064384A5016806564 @default.
• W3201064384 hasAuthorship W3201064384A5034894648 @default.
• W3201064384 hasAuthorship W3201064384A5048822014 @default.
• W3201064384 hasAuthorship W3201064384A5071037763 @default.
• W3201064384 hasAuthorship W3201064384A5082390639 @default.
• W3201064384 hasAuthorship W3201064384A5086682044 @default.
• W3201064384 hasConcept C106782819 @default.
• W3201064384 hasConcept C108225325 @default.

• next