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- W320139105 abstract "The retention behaviour of alkali and alkaline earth metal ions on a novel silica bonded macrocyclic calix[4]arene tetradiethylamide phase is reported using water-eluent based ion chromatography. Using a short column and water as the mobile phase, the silica bonded phase displays enhanced chromatographic selectivities for Ca2+ and Sr2+ over Mg2+− and Ba2+ and for Na+ over K+, Cs+ and Li+ in line with known complexation selectivity from stability constant and extraction data. Selected ternary mixtures of alkali and alkaline earths can be separated with the elution order Ca2+/Na+ > > K+ > Mg2+ using water modified with methanol or acetonitrile as the mobile phase." @default.
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- W320139105 date "1997-01-01" @default.
- W320139105 modified "2023-10-17" @default.
- W320139105 title "Water-eluent based Ion Chromatography on Silica Bonded Molecular Baskets" @default.
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- W320139105 doi "https://doi.org/10.1533/9781845698652.2.153" @default.
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