FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3201392203> ?p ?o ?g. }

• W3201392203 endingPage "238" @default.
• W3201392203 startingPage "226" @default.
• W3201392203 abstract "Although nanometer-sized aluminum hydroxide clusters (i.e., ϵ-Al13 , [Al13 O4 (OH)24 (H2 O)12 ]7+ ) command a central role in aluminum ion speciation and transformations between minerals, measurement of their translational diffusion is often limited to indirect methods. Here, 27 Al pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has been applied to the AlO4 core of the ϵ-Al13 cluster with complementary theoretical simulations of the diffusion coefficient and corresponding hydrodynamic radii from a boundary element-based calculation. The tetrahedral AlO4 center of the ϵ-Al13 cluster is symmetric and exhibits only weak quadrupolar coupling, which results in favorable T1 and T227 Al NMR relaxation coefficients for 27 Al PFGSTE NMR studies. Stokes-Einstein relationship was used to relate the 27 Al diffusion coefficient of the ϵ-Al13 cluster to the hydrodynamic radius for comparison with theoretical simulations, dynamic light scattering from literature, and previously published 1 H PFGSTE NMR studies of chelated Keggin clusters. This first-of-its-kind observation proves that 27 Al PFGSTE NMR diffusometry can probe symmetric Al environments in polynuclear clusters of greater molecular weight than previously considered." @default.
• W3201392203 created "2021-09-27" @default.
• W3201392203 creator A5006651636 @default.
• W3201392203 creator A5017457971 @default.
• W3201392203 creator A5040497496 @default.
• W3201392203 creator A5053179825 @default.
• W3201392203 creator A5063895265 @default.
• W3201392203 creator A5078743203 @default.
• W3201392203 creator A5088380075 @default.
• W3201392203 date "2021-10-14" @default.
• W3201392203 modified "2023-09-30" @default.
• W3201392203 title "²⁷Al NMR diffusometry of Al₁₃ Keggin nanoclusters" @default.
• W3201392203 cites W1905936943 @default.
• W3201392203 cites W1970826868 @default.
• W3201392203 cites W1974448901 @default.
• W3201392203 cites W1975360906 @default.
• W3201392203 cites W1977400292 @default.
• W3201392203 cites W1980716938 @default.
• W3201392203 cites W1981627552 @default.
• W3201392203 cites W1988522626 @default.
• W3201392203 cites W1995611452 @default.
• W3201392203 cites W1998584736 @default.
• W3201392203 cites W2005692644 @default.
• W3201392203 cites W2007613643 @default.
• W3201392203 cites W2022673999 @default.
• W3201392203 cites W2022803091 @default.
• W3201392203 cites W2030765885 @default.
• W3201392203 cites W2037343568 @default.
• W3201392203 cites W2038475538 @default.
• W3201392203 cites W2046506030 @default.
• W3201392203 cites W2048967679 @default.
• W3201392203 cites W2052276388 @default.
• W3201392203 cites W2059095536 @default.
• W3201392203 cites W2069127196 @default.
• W3201392203 cites W2077343713 @default.
• W3201392203 cites W2084761689 @default.
• W3201392203 cites W2092941218 @default.
• W3201392203 cites W2094132870 @default.
• W3201392203 cites W2094525604 @default.
• W3201392203 cites W2094917763 @default.
• W3201392203 cites W2112311198 @default.
• W3201392203 cites W2119827591 @default.
• W3201392203 cites W2133106650 @default.
• W3201392203 cites W2140483410 @default.
• W3201392203 cites W2152457419 @default.
• W3201392203 cites W2157989175 @default.
• W3201392203 cites W2286825624 @default.
• W3201392203 cites W2320799806 @default.
• W3201392203 cites W2323329504 @default.
• W3201392203 cites W2325054037 @default.
• W3201392203 cites W2417405724 @default.
• W3201392203 cites W2546174263 @default.
• W3201392203 cites W2549325680 @default.
• W3201392203 cites W2572968585 @default.
• W3201392203 cites W2608764816 @default.
• W3201392203 cites W2788451670 @default.
• W3201392203 cites W2805624136 @default.
• W3201392203 cites W2896249594 @default.
• W3201392203 cites W2898507012 @default.
• W3201392203 cites W2906424735 @default.
• W3201392203 cites W2908503497 @default.
• W3201392203 cites W2942798140 @default.
• W3201392203 cites W2948339708 @default.
• W3201392203 cites W2950630380 @default.
• W3201392203 cites W2991103255 @default.
• W3201392203 cites W2993223090 @default.
• W3201392203 cites W3021167467 @default.
• W3201392203 cites W3129614155 @default.
• W3201392203 cites W3138457432 @default.
• W3201392203 doi "https://doi.org/10.1002/mrc.5218" @default.
• W3201392203 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34536037" @default.
• W3201392203 hasPublicationYear "2021" @default.
• W3201392203 type Work @default.
• W3201392203 sameAs 3201392203 @default.
• W3201392203 citedByCount "2" @default.
• W3201392203 countsByYear W32013922032022 @default.
• W3201392203 countsByYear W32013922032023 @default.
• W3201392203 crossrefType "journal-article" @default.
• W3201392203 hasAuthorship W3201392203A5006651636 @default.
• W3201392203 hasAuthorship W3201392203A5017457971 @default.
• W3201392203 hasAuthorship W3201392203A5040497496 @default.
• W3201392203 hasAuthorship W3201392203A5053179825 @default.
• W3201392203 hasAuthorship W3201392203A5063895265 @default.
• W3201392203 hasAuthorship W3201392203A5078743203 @default.
• W3201392203 hasAuthorship W3201392203A5088380075 @default.
• W3201392203 hasBestOaLocation W32013922031 @default.
• W3201392203 hasConcept C100705429 @default.
• W3201392203 hasConcept C113196181 @default.
• W3201392203 hasConcept C116447816 @default.
• W3201392203 hasConcept C121332964 @default.
• W3201392203 hasConcept C1276947 @default.
• W3201392203 hasConcept C15744967 @default.
• W3201392203 hasConcept C159467904 @default.
• W3201392203 hasConcept C164866538 @default.
• W3201392203 hasConcept C178635117 @default.
• W3201392203 hasConcept C178790620 @default.
• W3201392203 hasConcept C185592680 @default.
• W3201392203 hasConcept C199360897 @default.

• next